Preparation of Salts (Cambridge (CIE) O Level Chemistry): Exam Questions

4 hours43 questions
11 mark

When solid sodium chloride is mixed with water, sodium chloride solution forms.

What name is given to the process of mixing a solid with water to form a solution?

  • Crystallising

  • Diluting

  • Dissolving

  • Melting

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21 mark

Different salts can be prepared by titrating an alkali with an aqueous acid.

Three pieces of apparatus, P, Q and R, used to measure volumes of liquid are shown below.

fig-1-q1b-1cho-1f-paper-1-nov-2021

What are the names of the three pieces of apparatus, P, Q and R?

 

P

Q

R

 A

pipette

burette

measuring cylinder

 B

burette

pipette

conical flask

 C

pipette

volumetric flask

burette

 D

burette

pipette

measuring cylinder

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    31 mark

    The chemical equation for the preparation of lead(II) sulfate is written below. 

    Pb(NO3)2  (___) + Na2SO4 (___) → PbSO4 (___) + 2NaNO3 (___)

    What are the state symbols for each substance in this reaction? 

    • aq, aq, s, aq

    • aq, aq, s, s

    • s, aq, aq, s

    • s, aq, s, aq

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    41 mark

    A student making copper sulfate crystals used the method shown. 

    q6

    Unreacted copper carbonate was left over as it had been added in excess.

    What is the reason for adding it in excess and what would step 3 be of this method?

     

    reason for adding in excess

    step 3

     A

    to produce a greater amount of salt crystals

    filtration

     B

    to improve the colour intensity of the crystals

    crystallisation

     C

    to ensure all the acid reacts

    filtration

     D

    to increase the rate of reaction

    evaporation

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      51 mark

      When an aqueous salt is crystallised, some water can be retained within the structure of the salt.

      What is the name given to the type of salt that forms?

      • anhydrous salt

      • dehydrated salt

      • hydrated salt

      • soluble salt

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      11 mark

      A student wanted to prepare copper(II) sulfate crystals by reacting solid copper(II) oxide to a solution of hot sulfuric acid.

      An extract from the method section of the experimental handout is shown below:

      Add the copper(II) oxide in small amounts to the hot acid in the reaction flask and stir until it is …..1…... When the reaction has gone to completion the copper(II) oxide will no longer …..2……, …..3….. and …..4….. the solution to obtain the copper(II) sulfate crystals.

       

      1

      2

      3

      4

      A

      in excess

      precipitate

      cool

      dissolve

      B

      in excess

      dissolve

      filter

      cool

      C

      reacting

      dissolve

      cool

      filter

      D

      reacting

      precipitate

      filter

      cool

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        21 mark

        Which of the following methods to prepare a salt can be achieved using a burette and a pipette?

        • Nitric acid and calcium carbonate to prepare calcium nitrate.

        • Sulfuric acid and copper(II) oxide to prepare copper(II) sulfate.

        • Hydrochloric acid and zinc to prepare zinc chloride.

        • Hydrochloric acid and potassium hydroxide to prepare potassium chloride.

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        31 mark

        Copper(II) sulfate can be prepared by reacting solid copper(II) carbonate with hot sulfuric acid. The alkali solid is always added in excess.

        Why is the solid reactant added in excess?

        • To ensure all of the acid reacts.

        • To make the reaction go faster.

        • To ensure all of the solid reactant has reacted.

        • To increase the product yield.

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        41 mark

        What is the correct sequence of steps for the preparation of a pure sample of lead(II) iodide from solid potassium iodide and lead(II) nitrate ?

        •  Mixing → Dissolving → Filtration → Rinsing with distilled water → Drying

        • Rinsing with distilled water → Dissolving → Mixing → Filtration → Drying

        • Dissolving → Mixing → Filtration → Rinsing with distilled water → Drying

        • Dissolving → Filtration →  Mixing → Rinsing with distilled water → Drying

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        51 mark

        Samples of two solids, P & Q, are separately dissolved in water and made into solutions.

        Which combination of P & Q solutions, would give an insoluble product on mixing?

         

        P

        Q

        A

        potassium chloride

        sodium hydroxide

        B

        ammonium chloride

        potassium sulfate

        C

        sodium nitrate

        magnesium sulfate

        D

        barium chloride

        sodium sulfate

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          61 mark

          Two incomplete statements about the preparation of an insoluble salt are given.

          ......1...... can be used to prepare insoluble salts, such as ......2...... .

          The salt is collected by ...... 3...... and it is then ......4...... .

          Which words correctly complete gaps 1–4?

           

          1

          2

          3

          4

          A

          precipitation

          barium nitrate

          filtration

          evaporated

          B

          precipitation

          lead sulfate

          evaporation

          washed and dried

          C

          precipitation

          lead sulfate

          filtration

          washed and dried

          D

          titration

          barium nitrate

          evaporation

          washed and dried

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            71 mark

            Which pair of reagents is suitable for preparing a pure sample of copper(II) chloride crystals?

            • aqueous copper(II) nitrate and aqueous sodium chloride

            • copper and aqueous sodium chloride

            • copper and dilute hydrochloric acid

            • copper(II) oxide and dilute hydrochloric acid

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            11 mark

            A student is provided with solutions of dilute hydrochloric acid, dilute sulfuric acid, solid magnesium oxide, zinc carbonate and copper.

            How many different salts could the student make?

            • 2

            • 3

            • 4

            • 6

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            21 mark

            A substance reacts with dilute H2SO4 to form a salt which is separated by filtration.

            What is the substance?

            • Aqueous sodium hydroxide

            • Aqueous barium chloride

            • Copper

            • Copper(II) carbonate

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            31 mark

            Which statement is correct?

            • Anhydrous copper sulfate will decrease in mass on gentle warming

            • Water of crystallisation is the number of water molecules present in hydrated crystals

            • All soluble salts contain water of crystallisation 

            • Hydrated copper(II) sulfate has the formula CuSO4.2H2O

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            41 mark

            Which method(s) of salt preparation could be used to prepare a sample of magnesium chloride?

            1   Titration

            2   Reaction of an acid with excess metal

            3  Reaction of an acid with excess insoluble base

            • 1 and 2 only

            • 1 and 3 only

            • 2 and 3 only

            • 1 only

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            51 mark

            Silver chloride can be prepared by the reaction of silver nitrate solution with potassium chloride solution.

            Which statement about the preparation is correct?

            • To get the maximum yield of product you need to have excess silver nitrate

            • To get the maximum yield of product you need to have excess potassium chloride

            • Equal volumes of the two solutions should be used

            • Equal concentrations of the two solutions should be used

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