Calculating Concentration (Cambridge (CIE) O Level Chemistry): Revision Note
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Units of Concentration
A solid substance that dissolves in a liquid is called a solute, the liquid is called a solvent and the two when mixed together form a solution
Most chemical reactions occur between solutes which are dissolved in solvents, such as water or an organic solvent
Concentration simply refers to the amount of solute there is in a specific volume of the solvent
The greater the amount of solute in a given volume, the greater the concentration
The amount of solute can be expressed in grams or moles
Typically, concentration is expressed in terms of the amount of substance per dm3, therefore the units of concentration are either: g/dm3 or mol/dm3
Calculating Concentration
Concentration refers to the amount of solute there is in a specific volume of the solvent
A general formula to calculate the concentration in g/dm3 is:
Concentration can be measured in grams per cubic decimetre
1 decimetre cubed (dm3) = 1000 cm3
1 decimetre cubed (dm3) is the same as 1 litre
You may be given data in a question which needs to be converted from cm3 to dm3 or the other way around
To go from cm3 to dm3 :
Divide by 1000
To go from dm3 to cm3 :
Multiply by 1000
Worked Example
A student dissolved 10 g of sodium hydroxide, NaOH, in 2 dm3 of distilled water. Calculate the concentration of the solution in g/dm3.
Answer
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Calculating Concentration using Moles
It is more useful to a chemist to express concentration in terms of moles per unit volume rather than mass per unit volume
Concentration can therefore be expressed in moles per decimetre cubed and calculated using the following equation:
We can modify the concentration formula to include moles
The units in the answer can be written as mol/dm3 (this can also be written as mol dm-3)
You may have to convert from g/dm3 into mol/dm3 and vice versa depending on the question
To go from g/dm3 to mol/dm3
Divide by the molar mass in grams
To go from mol/dm3 to g/dm3
Multiply by the molar mass in grams
Some students find formula triangles help them to understand the relationship:
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The concentration-moles formula triangle can help you solve these problems
Worked Example
Calculate the amount of solute, in moles, present in 2.5 dm3 of a solution whose concentration is 0.2 mol/dm3.
Answer
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Worked Example
Calculate the concentration of a solution of sodium hydroxide, NaOH, in mol/dm3, when 80 g is dissolved in 500 cm3 of water.
Relative atomic masses, Ar: Na= 23; H= 1; O= 16
Answer
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Worked Example
25.0 cm3 of 0.050 mol/dm3 sodium carbonate was completely neutralised by 20.00 cm3 of dilute hydrochloric acid. Calculate the concentration in mol/dm3 of the hydrochloric acid.
Answer
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Examiner Tips and Tricks
Remember to always convert the units from cm3 to dm3 by dividing by 1000.
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