Entropy: A Level Chemistry Definition
Written by: Alexandra Brennan
Reviewed by: Philippa Platt
Published
Last updated
What is entropy?
Entropy (S) is a measure of the disorder or randomness of a system. The greater the disorder, the higher the entropy.
In A Level Chemistry, entropy is crucial for understanding spontaneity in chemical reactions. Gases have higher entropy than liquids and solids due to the greater freedom of particle movement. Entropy change (ΔS) is positive when a system becomes more disordered, such as when a solid dissolves or a reaction produces more gas molecules.
Entropy change can be calculated using:
ΔSsystemꝋ = ΣΔSproductsꝋ - ΣΔSreactantsꝋ
(where Σ = sum of)
The feasibility of a reaction depends on both entropy and enthalpy, as shown in the Gibbs free energy equation (ΔG = ΔH - TΔS). Understanding entropy helps explain why some reactions occur spontaneously, even if they are endothermic.
Entropy Revision Resources to Ace Your Exams
For more information about entropy check out the following resources:
Sign up for articles sent directly to your inbox
Receive news, articles and guides directly from our team of experts.
Share this article