Entropy: A Level Chemistry Definition

Alexandra Brennan

Written by: Alexandra Brennan

Reviewed by: Philippa Platt

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What is entropy?

Entropy (S) is a measure of the disorder or randomness of a system. The greater the disorder, the higher the entropy.

In A Level Chemistry, entropy is crucial for understanding spontaneity in chemical reactions. Gases have higher entropy than liquids and solids due to the greater freedom of particle movement. Entropy change (ΔS) is positive when a system becomes more disordered, such as when a solid dissolves or a reaction produces more gas molecules.

Entropy change can be calculated using:

ΔSsystem= ΣΔSproducts - ΣΔSreactants

(where Σ = sum of)

The feasibility of a reaction depends on both entropy and enthalpy, as shown in the Gibbs free energy equation (ΔG = ΔH - TΔS). Understanding entropy helps explain why some reactions occur spontaneously, even if they are endothermic.

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Alexandra Brennan

Author: Alexandra Brennan

Expertise: Chemistry

Alex studied Biochemistry at Newcastle University before embarking upon a career in teaching. With nearly 10 years of teaching experience, Alex has had several roles including Chemistry/Science Teacher, Head of Science and Examiner for AQA and Edexcel. Alex’s passion for creating engaging content that enables students to succeed in exams drove her to pursue a career outside of the classroom at SME.

Philippa Platt

Author: Philippa Platt

Expertise: Chemistry

Philippa has worked as a GCSE and A level chemistry teacher and tutor for over thirteen years. She studied chemistry and sport science at Loughborough University graduating in 2007 having also completed her PGCE in science. Throughout her time as a teacher she was incharge of a boarding house for five years and coached many teams in a variety of sports. When not producing resources with the chemistry team, Philippa enjoys being active outside with her young family and is a very keen gardener

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