Amount of Substance (Edexcel International AS Chemistry)

Exam Questions

51 mins23 questions
1
Sme Calculator
1 mark

The high resolution mass spectrum of a compound X has a molecular ion peak at m / z = 44.0632. Accurate relative atomic masses are given in the table. 

Element Relative atomic mass
Hydrogen 1.0079
Carbon 12.0000
Oxygen 15.9949

Which of these compounds, with a relative molecular mass of 44, gives rise to this peak? 

q12-paper-4-2021-june-edexcel-ial-chemistry

    Did this page help you?

    1a
    Sme Calculator
    1 mark

    The maximum permitted concentration of sulfur in diesel fuel is 10 mg of sulfur in 1 kg of diesel fuel.

    a)
    What is this concentration of sulfur in ppm?

    • 0.00001

    • 0.01

    • 10

    • 10000

    1b
    Sme Calculator
    1 mark
    b)

    3.2 kg of this diesel fuel is burned in air.

    What is the maximum volume, in dm3, of sulfur dioxide which can be produced, measured at room temperature and pressure (r.t.p.)?

    [Molar volume of a gas at r.t.p. = 24 dm3 mol−1]

    • 0.024

    • 0.77

    • 2.4

    • 24

    Did this page help you?

    2
    Sme Calculator
    1 mark

    A mass of 4.179 g of hydrated iron(III) sulfate, Fe2(SO4)3·H2O, was dissolved in deionised water and the solution made up to 200 cm3 .

    What is the concentration of sulfate ions, SO42-, in the solution, in mol dm−3?

    [Molar mass of Fe2(SO4)3·H2= 417.9 g mol−1]

    • 0.01

    • 0.05

    • 0.10

    • 0.15

    Did this page help you?

    3a
    Sme Calculator
    1 mark

    A mass of 0.23 g of sodium was added to 350 cm3 water to form hydrogen and a solution of sodium hydroxide.

    Na (s) + H2O (l) → NaOH (aq) + 1⁄2H2 (g)

    a)
    What is the concentration, in mol dm−3, of sodium hydroxide in the solution formed?

    • 0.010

    • 0.029

    • 0.29

    • 0.66

    3b
    Sme Calculator
    1 mark
    b)

    What is the maximum volume, in cm3, of hydrogen which could be formed, measured at r.t.p.?

    [Molar volume of a gas at r.t.p. = 24 dm3 mol−1]

    • 120

    • 240

    • 480

    • 2800

    3c1 mark
    c)

    The sodium hydroxide solution was neutralised with sulfuric acid.

    Which is the ionic equation for this reaction?

    • H+ (aq) + OH(aq) → H2O (l)

    • Sbegin mathsize 16px style O subscript 4 to the power of 2 minus sign end style (aq) + 2Na+ (aq) → Na2SO4 (aq)

    • H2SO4 (aq) + 2Na+ (aq) + 2OH(aq) → Na2SO4 aq) + 2H2O (l)

    • 2H+ (aq) + Sstraight O subscript 4 superscript 2 minus end superscript (aq) + 2Na+ (aq) + 2OH(aq) → 2Na+ (aq) + Sstraight O subscript 4 superscript 2 minus end superscript (aq) + 2H2O (l)

    3d
    Sme Calculator
    1 mark
    d)
    Sodium hydroxide solution was added to magnesium sulfate solution.

    The equation for the reaction is shown.

    2NaOH(aq) + MgSO4(aq) → Mg(OH)2(s) + Na2SO4(aq)

    What is the atom economy (by mass) for the production of magnesium hydroxide?

    [Ar values: H = 1.0 O = 16.0 Na = 23.0 Mg = 24.3 S = 32.1]

    • 29.1%

    • 41.0%

    • 48.4%

    • 50.0%

    Did this page help you?

    4
    Sme Calculator
    1 mark

    Which conversion has the lowest percentage atom economy (by mass) for the formation of CaCl2?

    • Ca + Cl2 → CaCl2

    • Ca + 2HCl → CaCl2 + H2

    • CaCO3 + 2HCl → CaCl2 + H2O + CO2

    • CaCO3 + 2NaCl → CaCl2 + Na2CO3

    Did this page help you?

    5
    Sme Calculator
    1 mark

    The concentration of nitrogen dioxide in a sample of air is 0.5 ppm.
    What is the percentage of nitrogen dioxide molecules in this sample of air?

    • 0.5%

    • 0.005%

    • 0.00005%

    • 0.0000005%

    Did this page help you?

    6
    Sme Calculator
    1 mark

    The equation for the complete combustion of propan-1-ol is shown.

    C3H7OH(l) + 4 1⁄2O2(g) → 3CO2(g) + 4H2O(l)

    2.00 × 10−3 mol of propan-1-ol undergoes complete combustion.

    What mass of carbon dioxide is formed?

    • 0.0293g

    • 0.0880g

    • 0.132g

    • 0.264g

    Did this page help you?

    7
    Sme Calculator
    1 mark

    A student is provided with 25.0 cm3 of 1.00 mol dm–3 hydrochloric acid.

    What volume of distilled water should the student add to this solution to make a 0.0500 mol dm–3 solution?

    • 25.0 cm3

    • 50.0 cm3

    • 475 cm3

    • 500 cm3

    Did this page help you?

    8
    Sme Calculator
    1 mark

    Iron(III) oxide is reduced by hydrogen in a two-step process.

    Step 1: 3Fe2O3 + H2 → 2Fe3O4 + H2O
    Step 2: Fe3O4 + 4H2 → 3Fe + 4H2O


    What is the maximum mass of iron that could be produced from 39.9 tonnes of Fe2O3 ?
    [Ar values: H = 1.0 O = 16.0 Fe = 55.8]   

    • 6.98 tonnes

    • 13.95 tonnes

    • 27.90 tonnes

    • 41.85 tonnes

    Did this page help you?

    9
    Sme Calculator
    1 mark

    Which of these gases occupies 6.0 dm3 at room temperature and pressure (r.t.p.)?

    [molar volume of gas at r.t.p. = 24.0 dm3 mol−1

    Ar values: He = 4.0 C = 12.0 N = 14.0 O = 16.0]

    • 2.0 g of helium

    • 4.0 g of oxygen

    • 11.0 g of carbon dioxide

    • 14.0 g of nitrogen

    Did this page help you?

    10
    Sme Calculator
    1 mark

    How many moles are there in 15.1 cm3 of liquid propan-1-ol?

    [Density of propan-1-ol = 0.80 g cm−3      Mr of propan-1-ol = 60]

    • (0.80 × 15.1) ÷ 60

    • 0.80 ÷ (60 × 15.1)

    • 60 ÷ (0.80 × 15.1)

    • (60 × 15.1) ÷ 0.80

    Did this page help you?

    11
    Sme Calculator
    1 mark

    Which of these solutions contains the greatest number of ions?

    • 20.0 cm3 of 0.5 mol dm−3 KCl

    • 0.40 dm3 of 0.03 mol dm−3 KCl

    • 10.0 cm3 of 0.6 mol dm−3 CaCl2

    • 0.15 dm3 of 0.04 mol dm−3 CaCl2

    Did this page help you?

    12
    Sme Calculator
    1 mark

    What volume, in dm3, of hydrogen gas will be produced when 3.00 g of lithium is reacted with water at room temperature and pressure (r.t.p.)?

    2Li + 2H2O → 2LiOH + H2

    [Molar volume of gas at r.t.p. = 24.0 dm3 mol–1]

    • 0.217

    • 0.435

    • 5.22

    • 10.4

    Did this page help you?

    13
    Sme Calculator
    1 mark

    Potassium chlorate(V) decomposes on heating to form oxygen.

    2KClO3 → 2KCl + 3O2

    What is the atom economy (by mass) for the formation of oxygen?
    [Ar values: O = 16.0 Cl = 35.5 K = 39.1]

    • 13.1%

    • 26.1%

    • 39.2%

    • 64.3%

    Did this page help you?

    14
    Sme Calculator
    1 mark

    10.00 g of hydrated magnesium sulfate, MgSO4•7H2O, is heated to remove the water of crystallisation.

    What mass of anhydrous magnesium sulfate, MgSO4, is formed?

    [Molar mass of MgSO4•7H2O = 246.4 g mol−1 ]

    • 2.84 g

    • 4.89 g

    • 5.11 g

    • 7.16 g

    Did this page help you?

    15
    Sme Calculator
    1 mark

    Propane burns completely in oxygen as shown.

    C3H8 (g) + 5O2 (g) → 3CO2 (g) + 4H2O (l)

    100 cm3 of propane was mixed with 600 cm3 of oxygen and the mixture was ignited.

    What is the total volume, in cm3, of the gas mixture at the end of the reaction?

    All gas volumes were measured at room temperature and pressure.

    • 300

    • 400

    • 700

    • 800

    Did this page help you?

    16
    Sme Calculator
    1 mark

    Barium chloride solution, BaCl2 (aq), reacts with gallium sulfate solution, Ga2(SO4)3 (aq) to form a precipitate of barium sulfate, BaSO4 (s).

    What is the minimum volume of 0.100 mol dm−3 barium chloride needed to precipitate all the sulfate ions in 200 cm3 of 0.05 mol dm−3 gallium sulfate?

    • 100 cm3

    • 200 cm3

    • 300 cm3

    • 400 cm3

    Did this page help you?

    17
    Sme Calculator
    1 mark

    Which aqueous solution contains the greatest number of ions?

    • 200 cm3 of 1.5 mol dm−3 MgCl2

    • 400 cm3 of 0.8 mol dm−3 MgSO4

    • 500 cm3 of 1.0 mol dm−3 NaCl

    • 1000 cm3 of 0.25 mol dm−3 Na2SO4

    Did this page help you?

    1
    Sme Calculator
    1 mark

    Which aqueous solution has the highest concentration, in mol dm-3, of chloride ions?

    • 0.1 g dm-3 HCl

    • 0.1 g dm-3 NaCl

    • 0.1 g dm-3 KCl

    • 0.1 g dm-3 BaCl2

    Did this page help you?

    2
    Sme Calculator
    1 mark

    A 4.00 mol dm−3 solution of an acid is used to prepare dilute solutions of the acid.

    What volume of water is required to make up 150 cm3 of 0.35 mol dm−3 solution of the acid?

    • 13.1 cm3

    • 52.5 cm3

    • 97.5 cm3

    • 136.9 cm3

    Did this page help you?