Oxidation & Reduction (Edexcel International AS Chemistry)

• Oxidation and reduction in a reaction can be demonstrated in terms of electron transfer
  • For example:

2NH₃ + 3Br₂ → N₂ + 6HBr

• The oxidation number of N in NH₃ has changed from -3 to 0
  
  • As the oxidation number has increased, nitrogen has been oxidised
• The oxidation number of Br has changed from 0 to -1 
  • As the oxidation number has decreased, bromine has been reduced 
• Overall, nitrogen has reduced bromine by donating electrons 

Oxidising agent

• An oxidising agent is a substance that oxidises another atom or ion by causing it to lose electrons
• An oxidising agent itself gets reduced – gains electrons
• Therefore, the ox. no. of the oxidising agent decreases

Example of an oxidising agent in a chemical reaction

Reducing agent

• A reducing agent is a substance that reduces another atom or ion by causing it to gain electrons
• A reducing agent itself gets oxidised – loses / donates electrons
• Therefore, the ox. no. of the reducing agent increases

Example of a reducing agent in a chemical reaction

• For a reaction to be recognised as a redox reaction, there must be both an oxidising and reducing agent
• Some substances can act both as oxidising and reducing agents
• Their nature is dependent upon what they are reacting with and the reaction conditions

Answer:

• • The correct option is 2
  • Oxidising agents are substances that oxidise other species, gain electrons and are themselves reduced.
  • Write down the oxidation numbers of each species in the reaction

• • In equation 2, Fe²⁺ oxidises Mg(0) to Mg²⁺(+2) and is itself reduced from Fe²⁺(+2) to Fe(0)