Rates of Reaction - Titrimetric Method (Edexcel International A Level Chemistry)

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Core Practical 9a: Titrimetric Methods

  • The reaction between iodine in an acidic solution and propanone is

CH3COCH(aq) + I2 (aq) → CH3COCH2I (aq) + H+ (aq) + I(aq) 

  • We can follow the rate of this reaction by using a continuous monitoring method and therefore we will be able to deduce the order of reaction with respect to a substance using a concentration line graph 
  • We can calculate the order of reaction with respect to iodine as the propanone and acid are in a large excess so their concentration do not change during the reaction 
  • Once a portion of the reaction mixture has been removed, we stop the reaction by adding sodium hydrogencarbonate
  • Performing a titration again sodium thiosulfate(VI) solution and using starch as an indicator is used to determine the concentration of iodine

2S2O32- (aq) + I2 (aq) → 2I- (aq) + S4O62- (aq) 

Steps in the procedure 

  • Mix 25 cm3 of 1.0 mol dm-3 aqueous propanone with 25 cm3 of 1.0 mol dm-3 sulfuric acid in a beaker 
  • Add 50 cm3 of 0.02 mol dm-3 iodine solution
  • Start the stop clock as soon this is added to the beaker
  • Using a pipette, withdraw 10 cm3 portion of the reaction mixture and transfer this to a conical flask 
    • Stop this portion of the reaction by adding a spatula of sodium hydrogen carbonate
  • Titrate this sample against 0.01 mol dm-3 sodium thiosulfate(VI) solution using starch as an indicator 
    • Record your result
  • Withdraw 10 cm3 of the reaction mixture every 3 minutes and repeat the process of stopping the reaction and titrating against the sodium thiosulfate(VI) solution 

Practical tips

  • Note the time at which the sodium hydrogencarbonate is added to the withdrawn portions of reaction mixture as this is when the reaction will be stopped and the concentration of iodine can be calculated accurately
  • Keep the clock running and note the time throughout the practical rather than stopping the clock 
  • Have everything ready and set up before beginning the procedure

Results

Sample Data from the Reaction

edexcel-8-1-3-results-table

  • This graph is a straight line graph
    • As the gradient is constant, the rate of reaction is constant, and therefore independent of the concentration of the iodine solution
    • This means the reaction is zero order with respect to the iodine
    • The rate equation for the reaction is
      • Rate = k[CH3COCH(aq)] [H(aq)]

Reaction Kinetics - Zero Order Concentration, downloadable AS & A Level Chemistry revision notes

Concentration-time graphs of a zero-order reaction

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Richard

Author: Richard

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Richard has taught Chemistry for over 15 years as well as working as a science tutor, examiner, content creator and author. He wasn’t the greatest at exams and only discovered how to revise in his final year at university. That knowledge made him want to help students learn how to revise, challenge them to think about what they actually know and hopefully succeed; so here he is, happily, at SME.