Isotopes (Oxford AQA IGCSE Combined Science Double Award)

Revision Note

Isotopes

  • Although the number of protons in a particular element is always the same, the number of neutrons can be different

  • Isotopes are atoms of the same element that have the same number of protons but a different number of neutrons

  • Isotopes of the same element therefore have the same atomic number but different mass numbers

  • In the diagram below are three isotopes of hydrogen:

Isotopes of hydrogen

The atomic structure of three isotopes of hydrogen
Hydrogen has three isotopes, each with a different number of neutrons but the same number of protons
  • Isotopes occur naturally, but some are more rare than others

  • For example, about 2 in every 10,000 hydrogen atoms are deuterium

    • Tritium is even more rare (about 1 in every billion billion hydrogen atoms)

Examiner Tips and Tricks

This topic is also covered in Chemistry, although some of the terminologies may be a little different. However, in Physics you must refer to neutrons when explaining isotopes.

  • The number of neutrons in an atom does not affect the chemical properties of an atom, such as its charge, but only its mass

    • This is because neutrons have no charge but do have mass

  • In the periodic table, the mass number of chlorine is often given as 35.5

A section of the periodic table

The periodic table showing the mass number of chlorine as 35.5
This section of a periodic table shows chlorine as having a mass number of 35.5, but other elements have an integer mass number
  • The mass number of chlorine is given as 35.5 because it has 2 isotopes, one with a mass number of 35 and the other with a mass number of 37

  • Chlorine-35 is about three times more abundant than chlorine-37, so the given mass number of chlorine is closer to 35 than 37 because the mass number is a weighted average

  • The number of electrons and protons in different isotopes remains the same

  • Some isotopes are unstable as they have an imbalance of protons and neutrons

Worked Example

State the number of protons, neutrons and electrons in chlorine-35 and chlorine-37 atoms.

Answer:

Step 1: Determine the number of protons

  • The atomic number is the number of protons

  • Both chlorine-35 and chlorine-37 have 17 protons

Step 2: Determine the number of neutrons

  • The mass number is the number of protons and neutrons

  • Chlorine-35 neutrons: 35 - 17 = 18 neutrons

  • Chlorine-37 neutrons: 37 - 17 = 20 neutrons

Step 3: Determine the number of electrons

  • The number of electrons is equal to the number of protons

  • Both chlorine-35 and chlorine-37 have 17 electrons

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