Homologous Series (Cambridge (CIE) IGCSE Co-ordinated Sciences (Double Award)): Revision Note

Homologous series

  • A homologous series is a family of organic compounds that have similar features and chemical properties due to them having the same functional group

  • The functional group is a group of atoms which are bonded in a specific arrangement that is responsible for the characteristic reactions of each member of a homologous series

Table of compounds & their functional groups

Family

Functional Group

Name ends in...

Alkane

C-C

-ane

Alkene

C=C

-ene

Alcohol

-OH

-ol

Examiner Tips and Tricks

Make sure you can identify the functional group for each homologous series.

General characteristic of homologous series

Extended tier only

  • All members of a homologous series have:

    • The same general formula

    • Same functional group

    • The difference in the molecular formula between one member and the next is CH2

  • These characteristics are shown below for ethanol and propanol, which belong to homologous series, alcohols

Table of characteristics of ethanol and propanol

 

Ethanol

Propanol

Molecular formula

CH3CH2OH

CH3CH2CH2OH

General formula

CnH2n+1OH

CnH2n+1OH

Functional group 

-OH

-OH

Boiling point (oC) 

78

97

Examiner Tips and Tricks

Make sure you learn the general formula for each homologous series.

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