Covalent Bonding (Oxford AQA IGCSE Combined Science Double Award)
Revision Note
Written by: Alexandra Brennan
Reviewed by: Stewart Hird
What is Covalent Bonding?
Non-metal atoms can share electrons with other non-metal atoms to obtain a full outer shell of electrons
When two atoms share pairs of electrons, they form covalent bonds
Covalent bonds between atoms are very strong
When two or more atoms are covalently bonded together, they form ‘molecules’
Covalently bonded substances may consist of simple molecules or giant molecules (also known as macromolecules)
Simple molecules include oxygen and water
Giant covalent structures include diamond and silicon dioxide
Weak intermolecular forces exist between individual molecules
For example, in methane, each molecule consists of four hydrogen atoms covalently bonded to a carbon atom, and in between individual methane molecules there are weak intermolecular forces
Shared electrons are called bonding electrons and occur in pairs
Electrons on the outer shell which are not involved in the covalent bond(s) are called non-bonding electrons
Covalent Bonding Diagram
Examiner Tips and Tricks
A key difference between covalent bonds and ionic bonds is that in covalent bonds the electrons are shared between the atoms, they are not transferred (donated or gained) and no ions are formed.
Simple Covalent Molecules
Covalent substances tend to have simple molecular structures
These small molecules are known as simple molecules
Small covalent molecules can be represented by dot and cross diagrams
You need to be able to describe and draw the correct dot-and-cross diagrams, as shown, for the following molecules:
Hydrogen (H2)
Chlorine (Cl2)
Oxygen (O2)
Nitrogen (N2)
Hydrogen chloride (HCl)
Water (H2O)
Ammonia (NH3)
Methane (CH4)
Examiner Tips and Tricks
Each covalent bond represents one shared pair of electrons.
For example, there are two covalent bonds between the two oxygen atoms in O2 so four electrons are shared.
Extension Tier Only
Other simple molecules and giant structures can be given
This will be shown by a shared pair of electrons or the line(s) for the covalent bond between atoms
Ethene dot-and-cross diagram
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