Tests for Cations (Edexcel IGCSE Science (Double Award))
Revision Note
Written by: Stewart Hird
Reviewed by: Lucy Kirkham
Tests for cations
Metal cations in aqueous solution can be identified by the colour of the precipitate they form on addition of sodium hydroxide
If only a small amount of NaOH is used then normally the metal hydroxide precipitates
The table below contains the results for each of the cations included in the syllabus
If a precipitate is formed from NaOH then the hydroxide is insoluble in water
Metal ion | Effect of adding NaOH |
---|---|
Cu2+ | Light blue precipitate formed |
Fe2+ | Green precipitate formed |
Fe3+ | Brown precipitate formed |
NH4+ | Ammonia gas is produced which turns damp red litmus paper blue |
Examiner Tips and Tricks
Sometimes you may not see much of a precipitate because the cation you are testing is present is very small amounts. However, every a slight cloudiness or colour change can indicate a positive test result.
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