Calorimetry (Edexcel IGCSE Chemistry (Modular))

Calorimetry

• We can experimentally determine the relative amounts of energy released by a fuel 

• We do this using simple calorimetry

• There are two types of calorimetry experiments you need to know:

  • Enthalpy changes of reactions in solution

  • Enthalpy changes of combustion 

Reactions in solution

• To calculate the amount of energy produced by a chemical reaction in solution we measure the temperature change when the solutions are mixed together

• The solutions need to be mixed together in an insulated contain to prevent heat loss

• This method can be used for:

  • Neutralisation reactions

  • Dissolving solids in water

  • Displacement reactions

• For the purposes of the calculations, some assumptions are made about the experiment:

  • That the specific heat capacity of the solution is the same as pure water, i.e. 4.18 J/g/°C

  • That the density of the solution is the same as pure water, i.e. 1 g/cm³

  • The specific heat capacity of the container is ignored

  • The reaction is complete

  • There are negligible heat losses

• A calorimeter can be made up of a polystyrene drinking cup, a vacuum flask or metal can

A simple calorimeter 

A polystyrene cup can act as a calorimeter to find enthalpy changes in a chemical reaction

• Method:

  1. A fixed volume of one reagent is added to the calorimeter and the initial temperature taken with a thermometer

  2. An excess amount of the second reagent is added and the solution is stirred continuously

  3. The maximum temperature is recorded and the temperature rise calculated

• The energy released would be calculated using:

Q = m x c x ΔT

• Q = the heat energy change, J

• m = the mass of the substance being heated, g

• c = the specific heat capacity, J/g/°C

• ΔT = the temperature change, °C

Enthalpy of combustion experiments

• The principle here is to use the heat released by a combustion reaction to increase the heat content of water

• A typical simple calorimeter is used to measure the temperature changes to the water

Diagram to show the set up of calorimetry equipment

A lid is used to prevent heat loss

• The steps are: 

  1. Measure a fixed volume of water into a copper can

  2. Weigh the spirit burner containing  a fuel using a balance

  3. Measure the initial temperature of the water

  4. Burn the fuel and stir the water 

  5. Wait until the temperature has risen by approximately 20 ^oC and extinguish the flame

  6. Record the final temperature of the water and re-weigh the spirit burner

• To calculate the energy released by the fuel we can use the data obtained from the experiment above and the specific heat capacity of water 

• The specific heat capacity, c, is the energy needed to raise the temperature of 1 g of a substance by 1 °C

  • The specific heat capacity of water is 4.18 J/g/°C

• The heat energy change is calculated using:

Q = m x c x ΔT

• Q = the heat energy change, J

• m = the mass of the substance being heated, g

• c = the specific heat capacity, J/g/°C

• ΔT = the temperature change, °C

Sources of error

• Not all the heat produced by the combustion reaction is transferred to the water

  • Some heat is lost to the surroundings

  • Some heat is absorbed by the calorimeter

• To minimise the heat losses the copper calorimeter should not be placed too far above the flame and a lid placed over the calorimeter

• Shielding can be used to reduce draughts

• In this experiment the main sources of error are

  • Heat losses

  • Incomplete combustion