Reactions of Acids (Edexcel IGCSE Chemistry (Modular))

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Stewart Hird

Written by: Stewart Hird

Reviewed by: Lucy Kirkham

Reactions of Acids

Reactions of acids with metals

  • Only metals above hydrogen in the reactivity series will react with dilute acids

  • The more reactive the metal then the more vigorous the reaction will be

  • Metals that are placed high on the reactivity series such as potassium and sodium are very dangerous and react explosively with acids

  • When acids react with metals they form a salt and hydrogen gas

  • The general equation is:

metal + acid ⟶ salt + hydrogen

  • Some examples of metal-acid reactions and their equations are given below:

Table of acid-metal reactions

Metal

Sulfuric acid

Hydrochloric acid

 Magnesium 

 Mg (s) + H2SO4 (aq) → MgSO4 (aq) + H2 (g)

 Mg (s) + 2HCl (aq) → MgCl2 (aq) + H2 (g)

 Zinc

Zn (s) + H2SO4 (aq) → ZnSO4 (aq) + H2 (g) 

 Zn (s) + 2HCl (aq) → ZnCl2 (aq) + H2 (g)

 Iron

Fe (s) + H2SO4 (aq) → FeSO4 (aq) + H2 (g)

 Fe (s) + 2HCl (aq) → FeCl2 (aq) + H2 (g)

  • In general, we can summarise the reaction of a metal that forms a +2 ion as follows:

Acids-Metals Summary Table

Acid

Name of products

Equation for reaction

Hydrochloric acid

Metal chloride and hydrogen

M + 2HCl → MCl2 + H2

Sulfuric acid

Metal sulfate and hydrogen

M + H2SO4 → MSO4 + H2

Reaction of acids with bases

  • When an acid reacts with a base, a neutralisation reaction occurs

  • In all acid-base neutralisation reactions, a salt and water are produced:

acid + base ⟶ salt + water

  • The identity of the salt produced depends on the acid used and the positive ions in the base

  • Hydrochloric acid produces chlorides, sulfuric acid produces sulfate salts and nitric acid produces nitrates

  • Metal oxides and metal hydroxides act as bases

  • The following are some specific examples of reactions  between acids and metal oxides / hydroxides:

2HCl + CuO ⟶ CuCl2 + H2O

H2SO4 + 2NaOH ⟶ Na2SO4 + 2H2O

HNO3 + KOH ⟶ KNO3 + H2O

  • In general, we can summarise the reaction of metals and bases as follows:

Acids and Metals Oxides or Hydroxides Summary Table

Acid

Name of products

Equation for reaction

Hydrochloric acid

Metal chloride and water

MOH + HCl ⟶ MCl + H2O

Sulfuric acid

Metal sulfate and water

MO + H2SO4 ⟶ MSO4 + H2O

Nitric acid

Metal nitrate and water

MO + HNO3 ⟶ MNO3 + H2O

Reactions of Acids with Metal Carbonates

  • Acids will react with metal carbonates to form the corresponding metal saltcarbon dioxide and water

  • These reactions are easily distinguishable from acid – metal oxide/hydroxide reactions due to the presence of effervescence caused by the carbon dioxide gas

Acids & Metal Carbonates Reactions Table

Acid

Name of Products

Equation for Reaction

Hydrochloric acid

Metal chloride, carbon dioxide and water

MCO3 + 2HCl ⟶ MCl2 + CO2 + H2O

Sulfuric acid

Metal sulfate, carbon dioxide and water

MCO3 + 2H2SO4 ⟶ MSO4 + CO2 + H2O

Nitric acid

Metal nitrate, carbon dioxide and water

MCO3 + HNO3 ⟶ M(NO3)2 + CO2 + H2O

  • The following are some specific examples of reactions  between acids and metal carbonates:

2HCl + Na2CO3 ⟶ 2NaCl + H2O + CO2

H2SO4 + CaCO3⟶ CaSO4 + H2O + CO2

Examiner Tips and Tricks

If in an acid-base reaction there is effervescence produced then the base must be a metal carbonate which produces carbon dioxide gas.

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Stewart Hird

Author: Stewart Hird

Expertise: Chemistry Lead

Stewart has been an enthusiastic GCSE, IGCSE, A Level and IB teacher for more than 30 years in the UK as well as overseas, and has also been an examiner for IB and A Level. As a long-standing Head of Science, Stewart brings a wealth of experience to creating Topic Questions and revision materials for Save My Exams. Stewart specialises in Chemistry, but has also taught Physics and Environmental Systems and Societies.

Lucy Kirkham

Author: Lucy Kirkham

Expertise: Head of STEM

Lucy has been a passionate Maths teacher for over 12 years, teaching maths across the UK and abroad helping to engage, interest and develop confidence in the subject at all levels.Working as a Head of Department and then Director of Maths, Lucy has advised schools and academy trusts in both Scotland and the East Midlands, where her role was to support and coach teachers to improve Maths teaching for all.