Flame Tests (Edexcel IGCSE Chemistry: Double Science)

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Flame tests

  • The flame test is used to identify the positive metal ion (cations) by the colour of the flame they produce
    • Ions from different metals produce different colours
  • To carry out a flame test:
    • Dip the loop of an unreactive metal wire such as nichrome or platinum in dilute acid
    • Hold it in the blue flame of a Bunsen burner until there is no colour change
    • Dip the loop into the solid sample / solution and place it in the edge of the blue Bunsen flame
  • It is important to place the wire into acid first to prevent contamination
    • Not doing this might result in two or more ions being present on the wire meaning the colours will mix
    • One colour could mask another colour and you will not be able to identify the ion

Identifying Metal Cations, IGCSE & GCSE Chemistry revision notes

Diagram showing the technique for carrying out a flame test

  • The colour of the flame is observed and used to identify the metal ion present

Cation

Flame Colour

Li+

Red

Na+

Yellow

K+

Lilac

Ca2+

Orange-red

Cu2+

Blue-green

Colours of metal cations, IGCSE & GCSE Chemistry revision notes

Diagram showing the colours formed in the flame test for metal ions

Examiner Tip

The sample needs to be heated strongly, so the Bunsen burner flame should be on a blue flame.

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Stewart

Author: Stewart

Expertise: Chemistry Lead

Stewart has been an enthusiastic GCSE, IGCSE, A Level and IB teacher for more than 30 years in the UK as well as overseas, and has also been an examiner for IB and A Level. As a long-standing Head of Science, Stewart brings a wealth of experience to creating Exam Questions and revision materials for Save My Exams. Stewart specialises in Chemistry, but has also taught Physics and Environmental Systems and Societies.