Alkanes (CIE IGCSE Chemistry: Co-ordinated Sciences (Double Award))

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Alkanes: properties & bonding

  • Alkanes are a group of saturated hydrocarbons
  • The term saturated means that they only have single carbon-carbon bonds, there are no double bonds
  • Alkanes have covalent bonds as they consist of non-metal atoms 
  • The general formula of the alkanes is CnH2n+2
  • They are colourless compounds which have a gradual change in their physical properties as the number of carbon atoms in the chain increases
  • Alkanes are generally unreactive compounds but they do undergo combustion reactions, can be cracked into smaller molecules and can react with halogens in the presence of light in substitution reactions
  • Methane undergoes complete combustion forming carbon dioxide and water:

CH4 (g) + 2O(g) → CO2 (g) + 2H2O (l)

Table of alkanes

Displayed formula Name Molecular formula
methane methane CH4 
ethane ethane C2H6 
propane propane C3H8 
butane butane C4H10 
pentane pentane C5H12 

The first five members of the alkane homologous series

Examiner Tip

Co-ordinated students only need to be to name and draw the displayed formula for methane and ethane but extended students should know the whole table. 

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Alexandra

Author: Alexandra

Expertise: Chemistry

Alex studied Biochemistry at Newcastle University before embarking upon a career in teaching. With nearly 10 years of teaching experience, Alex has had several roles including Chemistry/Science Teacher, Head of Science and Examiner for AQA and Edexcel. Alex’s passion for creating engaging content that enables students to succeed in exams drove her to pursue a career outside of the classroom at SME.