Properties of Simple Molecules (Oxford AQA IGCSE Chemistry)

Revision Note

Melting & Boiling Points of Simple Molecules

  • Substances that consist of simple molecules are gases, liquid or solids with relatively low melting and boiling points 

  • They have strong covalent bonds between the atoms, but only weak forces between molecules

Diagram to show the difference between covalent and intermolecular bonds

The diagram highlights the covalent bond within a water a molecule, and the hydrogen bonding between water molecules
Covalent bonds are between atoms, intermolecular bonds are between molecules
  • They have relatively low melting and boiling points because: 

    • There are weak intermolecular forces between the molecules

    • These forces require little energy to overcome 

  • As the molecules increase in size, the melting and boiling points generally increase because the strength of these intermolecular forces increases and so more energy is needed to break them 

Examiner Tips and Tricks

Remember: When explaining their low melting and boiling point, it is not the covalent bonds between the atoms which are broken, but the weak intermolecular forces.

Conductivity of Simple Molecules

Simple molecules are poor conductors of electricity (even when molten) because:

  • There are no free ions or electrons to move and carry the charge.

  • Most covalent compounds do not conduct at all in the solid state and are thus insulators

  • Common insulators include the plastic coating around household electrical wiring, rubber and wood

Diagram showing how covalent materials are used as the insulating material in wires
The plastic coating around electrical wires is made from covalent molecules that do not allow a flow of charge

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