Properties of Ionic Compounds (Oxford AQA IGCSE Chemistry)
Revision Note
Written by: Alexandra Brennan
Reviewed by: Stewart Hird
Melting & Boiling Point of Ionic Compounds
Ionic compounds are made of charged particles called ions which form a giant lattice structure
Ionic compounds have high melting and boiling points because:
They have giant structures
There are strong electrostatic forces of attraction between oppositely charged ions in all directions
The forces need lots of energy to overcome them
The greater the charge on the ions, the stronger the electrostatic forces and the higher the melting point will be
For example, magnesium oxide consists of Mg2+ and O2- so will have a higher melting point than sodium chloride which contains the ions, Na+ and Cl-
Giant Ionic Lattice of Sodium Chloride
Examiner Tips and Tricks
Ions with higher charge have stronger electrostatic forces and will thus have higher melting and boiling points.
Conductivity of Ionic Compounds
For electrical current to flow there must be freely moving charged particles such as electrons or ions present
Ionic compounds are poor conductors in the solid state
The ions are in fixed positions in the lattice
They are therefore unable to move and carry a charge
Ionic compounds are good conductors of electricity in the molten state or in solution
When the ionic compound is melted or dissolved in water, the ions are able to move and carry a charge
Diagram to show the electrical conductivity of ionic compounds
Examiner Tips and Tricks
A common mistake students make in exams is to say that ionic compounds conduct electricity because 'electrons' move and carry a charge, when they should say the ions can move and carry a charge. Don't make that mistake!
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