Thermosoftening & Thermosetting Polymers (Oxford AQA IGCSE Chemistry)

Revision Note

Thermosoftening & Thermosetting Polymers

Extended Tier Only

  • Polymers can also be divided into thermosoftening and thermosetting polymers

  • Thermosetting polymers consist of chains which have strong cross-links between them

    • These polymers are strong and rigid structures that don’t melt when they are heated because lots of energy would be required to overcome the cross-links

    • They are commonly used in electrical plugs

  • Thermosoftening polymers consist of individual, tangled chains with no cross-links between them

    • These polymers therefore have low melting points, can be melted and remoulded to form different shapes

    • They are commonly used to make packaging and plastic bottles

    The structures of thermosetting and thermosoftening polymers

thermosoftening-v-thermosetting
Themosetting polymers have crosslinks in between polymer chains, but thermosoftening polymers don't

Examiner Tips and Tricks

If you are asked to explain the difference in properties, it is important to refer to the cross-links as it is the presence of these that affects the melting point of the polymer.

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