Phytomining & Bioleaching (Oxford AQA IGCSE Chemistry)

Phytomining

• Extraction of metal ores from the ground is only economically viable when the ore contains sufficiently high proportions of the useful metal, such as iron ores and aluminium ores

• For low grade ores (ores with lower quantities of metals) other techniques are being developed to meet global demand

• This is happening in particular with nickel and copper as their ores are becoming more and more scarce

• Phytomining and bioleaching (bacterial) are two relatively new methods of extracting metals that rely on biological processes

• Both of these methods avoid the significant environmental damage caused by the more traditional methods of mining

• Traditional mining involves a great deal of digging, moving and disposing of large amounts of rock

• Biological methods are, however, very slow and also require either displacement or electrolysis to purify the extracted metal

• Both techniques are also used to extract metals from mining wastes, which may contain small quantities of metals or toxic metals that need to be removed from that environment

What is Phytomining?

• This process takes advantage of how some plants absorb metals through their roots

• The plants are grown in areas known to contain metals of interest in the soil

• As the plants grow the metals are taken up through the plants vascular system and become concentrated in specific parts such as their shoots and leaves

• These parts of the plant are harvested, dried and burned

• The resulting ash contains metal compounds from which the useful metals can be extracted by displacement reactions or electrolysis

Process of Phytomining 

Bioleaching

What is Bioleaching?

• Bioleaching is a technique that makes use of bacteria to extract metals from metal ores

• Some strains of bacteria are capable of breaking down ores to form acidic solutions containing metals ions such as copper(II)

• The solution is called a leachate which contains significant quantities of metal ions

• The ions can then be reduced to the solid metal form and extracted by displacement reactions or electrolysis

• This method is often used to extract metals from sulfides e.g. CuS or Fe₂S

• Although bioleaching does not require high temperatures, it does produce toxic substances which need to be treated so they don’t contaminate the environment

• Bioleaching is not only used for the primary extraction of metals, but it is also used in mining waste clean up operations