How to Test for Gases (Edexcel IGCSE Chemistry (Modular))

Revision Note

Test yourself
Alexandra Brennan

Written by: Alexandra Brennan

Reviewed by: Stewart Hird

Tests for gases

  • Several tests for anions and cations produce gases which then need to be tested

  • The gases included in the syllabus are:

    • Ammonia

    • Carbon dioxide

    • Chlorine

    • Hydrogen

    • Oxygen

Test for ammonia

  • Ammonia is a gas with a characteristic sharp choking smell that turns damp red litmus paper blue

  • Hold the litmus paper near the mouth of the test tube, but be careful to avoid touching the sides of the test tube

  • If you are testing for ammonia produced from ammonium ions and sodium hydroxide, avoiding touching the sides to prevent traces of sodium hydroxide from also turning the red litmus paper blue

Testing for ammonia gas

The diagram shows a solution being heated to release ammonia gas, which turns damp red litmus paper blue

Damp red litmus paper turns blue in the presence of ammonia

Examiner Tips and Tricks

Make sure you understand the difference between ammonium and ammonia.

  • Ammonium refers to the aqueous cation, NH4+

  • Ammonia refers to the gas, NH3.

Test for carbon dioxide 

  • The test for carbon dioxide involves bubbling the gas through an aqueous solution of limewater (calcium hydoxide)

  • If the gas is carbon dioxide, the limewater turns cloudy white

Testing for carbon dioxide gas

The diagram shows damp blue litmus paper being placed into chlorine gas and then turning red before bleaching to a final white colour

Limewater turns cloudy white in the presence of carbon dioxide

Examiner Tips and Tricks

Sometimes students think that extinguishing a burning splint indicates carbon dioxide gas.

However, while it is a property of carbon dioxide, other gases, such as nitrogen, will also do this.

So, the test is not definitive and should not be given as an exam answer.

Test for chlorine gas

  • The test for chlorine makes use of litmus paper

  • If chlorine gas is present, damp blue litmus paper will turn red and then be bleached white

    • It turns red initially as acids are produced when chlorine comes into contact with water

  • Chlorine also has a characteristic sharp, choking smell 

  • Chlorine should always be handled in a fume cupboard due to its toxicity

Testing for chlorine gas

The diagram shows damp blue litmus paper being placed into chlorine gas and then turning red before bleaching to a final white colour

Chlorine bleaches damp blue litmus paper white

Examiner Tips and Tricks

You should distinguish between properties of gases and tests for gases. Chlorine 'smells like swimming pools' is a characteristic, but it is not an acceptable means of identification. 

Test for hydrogen gas

  • The test for hydrogen consists of holding a burning splint at the open end of a test tube of gas

  • If the gas is hydrogen it burns with a loud “squeaky pop” which is the result of the rapid combustion of hydrogen with oxygen to produce water

  • Be sure not to insert the splint right into the tube, just at the mouth, as the gas needs air to burn

Testing for hydrogen gas

The diagram shows a lit splint being placed at the neck of a test-tube of gas, and giving a sqeuaky pop sound for the presence of hydrogen

A burning splint gives a 'squeaky pop' sound

Examiner Tips and Tricks

It is easy to confuse the tests for hydrogen and oxygen.

Try to remember that a ligHted splint has an H for Hydrogen, while a glOwing splint has an O for Oxygen.

Test for oxygen

  • The test for oxygen consists of placing a glowing splint inside a test tube of gas

  • If the gas is oxygen, the splint will relight

Testing for oxygen gas

The diagram shows a glowing splint being added to a test-tube of oxygen, and the spling relights to confirm the presence of oxygen

A glowing splint will relight in the presence of oxygen

Examiner Tips and Tricks

Sometimes the splint does not relight, but it glows very brightly, which is also a positive result. In an exam, however, it is best to state it relights the glowing splint.

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Alexandra Brennan

Author: Alexandra Brennan

Expertise: Chemistry

Alex studied Biochemistry at Newcastle University before embarking upon a career in teaching. With nearly 10 years of teaching experience, Alex has had several roles including Chemistry/Science Teacher, Head of Science and Examiner for AQA and Edexcel. Alex’s passion for creating engaging content that enables students to succeed in exams drove her to pursue a career outside of the classroom at SME.

Stewart Hird

Author: Stewart Hird

Expertise: Chemistry Lead

Stewart has been an enthusiastic GCSE, IGCSE, A Level and IB teacher for more than 30 years in the UK as well as overseas, and has also been an examiner for IB and A Level. As a long-standing Head of Science, Stewart brings a wealth of experience to creating Topic Questions and revision materials for Save My Exams. Stewart specialises in Chemistry, but has also taught Physics and Environmental Systems and Societies.