Naming Organic Compounds (Edexcel IGCSE Chemistry (Modular))

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Stewart Hird

Written by: Stewart Hird

Reviewed by: Lucy Kirkham

Naming organic compounds

Names of compounds

  • The names of organic compounds have two parts: the prefix or stem and the end part (or suffix)

  • The prefix tells you how many carbon atoms are present in the longest continuous chain in the compound

  • The suffix tells you what functional group is on the compound

Examples of naming organic molecules

First part of name

Second part of name

Name

Number of carbon atoms

Name

Functional group

Family

Meth...

1

...ane

None

Alkane

Eth...

2

...ene

C=C bond

Alkene

Prop...

3

...anol

R-OH

Alcohol

But...

4

...anoic acid

R-C=O-OH

Carboxylic acid

Pent...

5

....amine

R-NH2

Amine

Hex...

6

...yl ...anoate

R-C=O-O-R

Ester

Further rules for naming compounds

  • When there is more than one carbon atom where a functional group can be located it is important to distinguish exactly which carbon the functional group is on

  • Each carbon is numbered and these numbers are used to describe where the functional group is

  • When 2 functional groups are present di- is used as a prefix to the second part of the name

Naming isomers 

An Introduction to AS Level Organic Chemistry Chain Isomerism, downloadable AS & A Level Chemistry revision notes

Isomers can be distinguished by following the naming rules

Examiner Tips and Tricks

You may not be asked to name branched chain organic compounds but you will come across them. It is useful to know that the numbers in the names of these compounds refer to the position of the side chains with respect to the main chain.

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Stewart Hird

Author: Stewart Hird

Expertise: Chemistry Lead

Stewart has been an enthusiastic GCSE, IGCSE, A Level and IB teacher for more than 30 years in the UK as well as overseas, and has also been an examiner for IB and A Level. As a long-standing Head of Science, Stewart brings a wealth of experience to creating Topic Questions and revision materials for Save My Exams. Stewart specialises in Chemistry, but has also taught Physics and Environmental Systems and Societies.

Lucy Kirkham

Author: Lucy Kirkham

Expertise: Head of STEM

Lucy has been a passionate Maths teacher for over 12 years, teaching maths across the UK and abroad helping to engage, interest and develop confidence in the subject at all levels.Working as a Head of Department and then Director of Maths, Lucy has advised schools and academy trusts in both Scotland and the East Midlands, where her role was to support and coach teachers to improve Maths teaching for all.