Ammonia is an important industrial chemical.
i) Give the electronic structure of an atom of nitrogen.
[1]
ii) Use this electronic structure, rather than the valency of nitrogen, to explain why the formula of ammonia is NH3, not NH4.
[2]
Separate: Chemistry and Extended Only
Ammonia is made by the Haber Process.
N2 (g) + 3H2 (g) 2NH3 (g)
The forward reaction is exothermic.
The percentage of ammonia in the equilibrium mixture varies with conditions.
Pressure/ atmospheres | 100 | 200 | 300 | 400 |
% ammonia at 300 °C | 45 | 65 | 72 | 78 |
% ammonia at 500 °C | 9 | 18 | 25 | 31 |
The conditions actually used are 200 atmospheres, 450 °C and an iron catalyst. Osmium was previously used as the catalyst for this process.
i) Suggest a reason why it was changed to iron.
[1]
ii) Explain why the highest pressure gives the highest percentage of ammonia in the equilibrium mixture.
[2]
iii) What happens to the unreacted nitrogen and hydrogen?
[1]
iv) State one advantage and one disadvantage of using a lower temperature.
advantage .................................................................................................................
disadvantage ..........................................................................................................
[2]
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