Exothermic & Endothermic Reactions (Cambridge (CIE) IGCSE Chemistry)

Exam Questions

4 hours36 questions
1a4 marks

A student investigated the addition of four different solids, A, B, C and D, to water. Five experiments were carried out.

Experiment 1

By using a measuring cylinder, 30 cm3 of distilled water was poured into a polystyrene cup and the initial temperature of the water was measured. 4 g of solid A was added to the cup and the mixture stirred with a thermometer. The temperature of the solution was measured after 2 minutes.

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Experiment 2

Experiment 1 was repeated using 4 g of solid B.

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Experiment 3

Experiment 1 was repeated using 4 g of solid C.

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Experiment 4

Experiment 1 was repeated using 4 g of solid D.

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Experiment 5

A little of the solution from Experiment 4 was added to a little of the solution from Experiment 2 in a test-tube. The observations were recorded.

Observations: A fast reaction. Vigorous effervescence and bubbles produced.

Use the thermometer diagrams for Experiments 1-4 to record the initial and final temperatures in Table 4.1. Calculate and record the temperature difference in Table 4.1.

Table 4.1 

experiment

temperature / °C

final temperature / °C

difference / °C

1

 

 

 

2

 

 

 

3

 

 

 

4

 

 

 

1b4 marks

Draw a labelled bar chart of the results to Experiments 1, 2, 3 and 4 on the grid below.

screen-shot-2022-09-28-at-11-57-05
1c2 marks

Use the results and observations from Experiments 1-5 to answer the following questions.

i) Which solid dissolves in water to produce an exothermic reaction?

[1]

ii) Give a reason why you chose this solid.

[1]

1d1 mark

Which Experiment produced the largest temperature change? 

1e4 marks

Predict the temperature change that would happen if

i) 8 g of solid B were used in Experiment 2

[1] 

ii) 60 cm3 of water was used in Experiment 4

[1] 

iii) Explain your answer to (e)(ii)

[2] 

1f2 marks

Suggest an explanation for the observations in Experiment 5. 

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2a5 marks

A student investigated what happened when sodium thiosulphate dissolved in water.

Experiment 1

By using a measuring cylinder, 20 cm3 of distilled water was poured into a polystyrene cup. Use the thermometer diagram to record the temperature of the water in the table.

1 g of powdered sodium thiosulphate was added to the cup and the mixture stirred with a thermometer. Use the thermometer diagram to record the temperature of the solution.

Experiment 2

Experiment 1 was repeated using 2 g of powdered sodium thiosulphate. Record the temperature in the table.

Experiments 3, 4 and 5

Experiment 1 was repeated using 3 g, 4 g and 5 g of powdered sodium thiosulphate respectively. Record the temperatures in the table.

5-1-q2a
2b4 marks

Plot the results of the experiments on the grid below. Draw a straight line graph. 

S9nCDrJt_5-1-q2b
2c4 marks

i) Use your graph to estimate the temperature of the reaction mixture if 3.5 g of powdered sodium thiosulphate were added to 20 cm3 of water.

Indicate clearly on the graph how you obtained your answer.

[2]

ii) From your graph work out the temperature of the reaction mixture if 6 g of powdered sodium thiosulphate were added to 20 cm3 of water.

Indicate clearly how you used your graph.

[2]

2d1 mark

What type of chemical reaction occurs when sodium thiosulphate dissolves in water?

2e2 marks

Explain how the temperature changes would differ in the experiments if 40 cm3 of water were used.

2f2 marks

Explain why the sodium thiosulphate was powdered before being used.

2g2 marks

Predict what the temperature of the reaction mixture in Experiment 5 would be after 1 hour. Explain your answer.

2h1 mark

Suggest one change you could make to the apparatus used in the experiments to obtain more accurate results.

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3a3 marks

A small piece of limestone was heated strongly and left to cool. A few drops of cold water were added. The solid expanded and gave off steam. 

heating-limestone

Complete the empty boxes to identify the pieces of apparatus labelled.

3b1 mark

What type of chemical reaction takes place when water is added?

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4a2 marks

A student investigated the reaction of aqueous sodium hydroxide with two different acids, acid C and acid D. Two experiments were carried out.

Experiment 1

By using a measuring cylinder, 20 cm3 of aqueous sodium hydroxide was poured into a conical flask and the initial temperature of the solution was measured.

A burette was filled with acid C up to the 0.0 cm3 mark.

5 cm3 of acid C was added to the sodium hydroxide in the flask. The temperature of the mixture was measured.

Further 5 cm3 portions of acid C were added to the mixture in the flask, stirring with the thermometer until a total volume of 30 cm3 of acid C had been added. The temperatures after each 5 cm3 portion had been added were measured.

Use the thermometer diagrams to record the temperatures in the table of results.

Table of results

5-1-q4a
4b2 marks

Experiment 2 The burette was emptied and rinsed with water. Experiment 1 was repeated using acid D

Use the thermometer diagrams to record the temperatures in the table of results.

Table of results

5-1-q4b
4c6 marks

Plot the results for Experiments 1 and 2 on the grid and draw two smooth line graphs. Clearly label your graphs.

5-1-q5c
4d2 marks

From your graph, deduce the temperature of the mixture when 3 cm3 of acid C reacted with sodium hydroxide in Experiment 1.

Show clearly on the graph how you worked out your answer.

4e3 marks

i) Which experiment produced the larger temperature change?

[1]

ii) Suggest why the temperature change is greater in this experiment.

[2]

4f1 mark

Why was the burette rinsed with water in Experiment 2?

4g2 marks

Predict the temperature of the reaction mixture in Experiment 2 after 1 hour. Explain your answer.

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5a1 mark

An experiment was carried out to measure the temperature changes during the neutralisation of sodium hydroxide solution with dilute hydrochloric acid. Both solutions were allowed to stand in the laboratory for about 30 minutes.

25 cm3 of sodium hydroxide solution was added to a polystyrene beaker and the temperature was measured. 10 cm3 of hydrochloric acid was added to the beaker and the highest temperature reached measured.

The experiment was repeated using different volumes of acid. 

Why were the solutions left to stand for about 30 minutes before the experiments?

5b1 mark

Why was a polystyrene beaker used instead of a glass beaker?

5c1 mark

The results of the experiments are shown plotted on the grid below.  

ZWnEhnaQ_5-1-q6c

What type of chemical reaction occurs when sodium hydroxide is neutralised by hydrochloric acid?

5d5 marks

i) Which point appears to be inaccurate?

[1]

ii) Draw two straight lines through the points and extend them until they cross.

[2]

iii) What volume of hydrochloric acid was needed to neutralise 25 cm3 of the sodium hydroxide solution?

[2]

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