Formulae (Cambridge (CIE) IGCSE Chemistry)

Revision Note

Caroline Carroll

Written by: Caroline Carroll

Reviewed by: Stewart Hird

Updated on

Molecular formulae

  • Elements are often represented using their chemical symbol from the Periodic Table

Chemical symbols of elements table

Element

Symbol

Element

Symbol

Lithium

Li

Calcium

Ca

Chromium

Cr

Gold

Au

Aluminium

Al

Sulfur

S

  • Seven elements exist as diatomic molecules, which means that they are molecules made of two atoms:

    1. Hydrogen, H2 

    2. Nitrogen, N2 

    3. Oxygen, O2 

    4. Fluorine, F2 

    5. Chlorine, Cl2 

    6. Bromine, Br2 

    7. Iodine, I2 

Periodic Table identifying the 7 diatomic elements

Periodic Table highlighting the seven elements that for diatomic molecules with the formula X2

The highlighted elements all exist as diatomic molecules with the formula X2

  • These 7 elements are also classed as simple molecules

  • Atoms combine together in fixed ratios that will give them full outer shells of electrons

    • When this happens, a molecule is formed

  • The molecular formula of a molecule shows:

    • The type of atoms involved, given by the chemical symbol
      AND

    • The number of atoms, given by the subscript (little) number after a chemical symbol

Examples of molecular formulae

Substance

Molecular formula

Made from

Hydrogen

H2

2 hydrogen atoms

Chlorine

Cl2

2 chlorine atoms

Water

H2

2 hydrogen atoms
1 oxygen atom

Methane

CH4

1 carbon atom
4 hydrogen atoms

Ammonia

NH3

1 nitrogen atom
3 hydrogen atoms

Sulfuric acid

H2SO4

2 hydrogen atoms
1 sulfur atom
4 oxygen atoms

  • The table also shows that the molecular formula can be deduced from the relative number of atoms present

    • E.g. Ammonia contains 3 atoms of hydrogen and 1 atom of nitrogen, which means its molecular formula is NH3

Diagrammatic representation of chemicals

  • Diagrams or models can be used to represent and/or deduce the molecular formula of elements and simple compounds:

Diagrams showing how chemicals can be represented visually

When simple molecules are represented using coloured atoms, a key is used to show the colours for each type of atom

  • Using the water examples, it is important to know that these representations also show the arrangement of the atoms in the molecule

    • Water, H2O

      • The hydrogen atoms are on either side of the oxygen atom

      • It does not have two hydrogen atoms and an oxygen atom all joined together in a row

Worked Example

What is the molecular formula of the following compound? 

butane

Answer:

  • The molecule contains:

    • 4 carbon atoms

    • 10 hydrogen atoms

  • Therefore, the molecular formula is C4H10 

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Caroline Carroll

Author: Caroline Carroll

Expertise: Physics Subject Lead

Caroline graduated from the University of Nottingham with a degree in Chemistry and Molecular Physics. She spent several years working as an Industrial Chemist in the automotive industry before retraining to teach. Caroline has over 12 years of experience teaching GCSE and A-level chemistry and physics. She is passionate about creating high-quality resources to help students achieve their full potential.

Stewart Hird

Author: Stewart Hird

Expertise: Chemistry Lead

Stewart has been an enthusiastic GCSE, IGCSE, A Level and IB teacher for more than 30 years in the UK as well as overseas, and has also been an examiner for IB and A Level. As a long-standing Head of Science, Stewart brings a wealth of experience to creating Topic Questions and revision materials for Save My Exams. Stewart specialises in Chemistry, but has also taught Physics and Environmental Systems and Societies.