Atomic Structure (Cambridge (CIE) IGCSE Chemistry)

What is atomic structure?

• All substances are made of tiny particles of matter called atoms which are the building blocks of all matter

• Each atom is made of subatomic particles called protons, neutrons, and electrons

• The protons and neutrons are located at the centre of the atom, which is called the nucleus

• The electrons move very fast around the nucleus in orbital paths called shells

• The mass of the electron is negligible, hence the mass of an atom is contained within the nucleus where the protons and neutrons are located

The structure of an atom

The structure of the carbon atom

Protons, neutrons & electrons

• The size of atoms is so tiny that we can't really compare their masses in conventional units such as kilograms or grams, so a unit called the relative atomic mass is used

• One relative atomic mass unit is equal to 1/12^th the mass of a carbon-12 atom.

• All other elements are measured relative to the mass of a carbon-12 atom, so relative atomic mass has no units 

• Hydrogen for example has a relative atomic mass of 1, meaning that 12 atoms of hydrogen would have exactly the same mass as 1 atom of carbon

 Table of subatomic particles

Defining proton number

• The atomic number (or proton number) is the number of protons in the nucleus of an atom

• The symbol for atomic number is Z

• It is also the number of electrons present in a neutral atom and determines the position of the element on the Periodic Table

Defining mass number

• The Nucleon number (or mass number) is the total number of protons and neutrons in the nucleus of an atom

• The symbol for nucleon number is A

• The nucleon number minus the proton number gives you the number of neutrons of an atom

• Note that protons and neutrons can collectively be called nucleons.

• The atomic number and mass number of an element can be shown using atomic notation

• The Periodic Table shows the elements together with their atomic (proton) number at the top and relative atomic mass at the bottom - there is a difference between relative atomic mass and mass number, but for your exam, you can use the relative atomic mass as the mass number (with the exception of chlorine)

Atomic number & mass number diagram

Diagram showing the notation used on the periodic table

How to calculate numbers of protons, neutrons and electrons

Protons

• The atomic number of an atom and ion determines which element it is

• E.g. lithium has an atomic number of 3 (three protons) whereas beryllium has atomic number of 4 (four protons)Therefore, all atoms and ions of the same element have the same number of protons (atomic number) in the nucleus

• The number of protons equals the atomic (proton) number

• The number of protons of an unknown element can be calculated by using its mass number and number of neutrons:

Mass number = number of protons + number of neutrons

Number of protons = mass number – number of neutrons

Electrons

• An atom is neutral and therefore has the same number of protons and electrons

Neutrons

• The mass and atomic numbers can be used to find the number of neutrons in ions and atoms:

Number of neutrons = mass number – number of protons