Entropy - GCSE Chemistry Definition

Reviewed by: Alexandra Brennan

Published

Last updated

What is entropy?

Entropy (S) is a measure of the disorder or randomness of a system. The greater the disorder, the higher the entropy.

In A Level Chemistry, entropy is crucial for understanding spontaneity in chemical reactions. Gases have higher entropy than liquids and solids due to the greater freedom of particle movement. Entropy change (ΔS) is positive when a system becomes more disordered, such as when a solid dissolves or a reaction produces more gas molecules.

Entropy change can be calculated using:

ΔSsystem= ΣΔSproducts - ΣΔSreactants

(where Σ = sum of)

The feasibility of a reaction depends on both entropy and enthalpy, as shown in the Gibbs free energy equation (ΔG = ΔH - TΔS). Understanding entropy helps explain why some reactions occur spontaneously, even if they are endothermic.

Entropy Revision Resources to Ace Your Exams

For more information about entropy check out the following resources:

Explore our A level Chemistry Revision Resources

Sign up for articles sent directly to your inbox

Receive news, articles and guides directly from our team of experts.

Share this article

Alexandra Brennan

Reviewer: Alexandra Brennan

Expertise: Chemistry

Alex studied Biochemistry at Newcastle University before embarking upon a career in teaching. With nearly 10 years of teaching experience, Alex has had several roles including Chemistry/Science Teacher, Head of Science and Examiner for AQA and Edexcel. Alex’s passion for creating engaging content that enables students to succeed in exams drove her to pursue a career outside of the classroom at SME.

The examiner written revision resources that improve your grades 2x.

Join now