Entropy - IB Physics Definition

Reviewed by: Ann Howell

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In IB Physics, the entropy S of a given system is a measure of the number of possible arrangements of the particles and their energies. In other words, it is a measure of how disordered a system is.

When a system becomes more disordered, its entropy will increase. The order of entropy for the different states of matter, from most disordered to least is:

gas > liquid > solid

The entropy of a substance changes during a change in state.

Graph showing entropy vs temperature for states of matter: solid, liquid, gas. Solid has lowest entropy, gas highest. Labels: melting and boiling points.
Solids have the lowest entropy and gases have the highest.

Entropy increases when a substance melts (solid → liquid) or boils (liquid → gas) . The particles in a gas can freely move around and are far apart from each other, and the entropy increases as the particles become more disordered.

Similarly, entropy decreases when a substance condenses (gas → liquid) or freezes (liquid → solid). The particles are brought together and become arranged more regularly, hence the entropy decreases.

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Ann Howell

Reviewer: Ann Howell

Expertise: Physics Content Creator

Ann obtained her Maths and Physics degree from the University of Bath before completing her PGCE in Science and Maths teaching. She spent ten years teaching Maths and Physics to wonderful students from all around the world whilst living in China, Ethiopia and Nepal. Now based in beautiful Devon she is thrilled to be creating awesome Physics resources to make Physics more accessible and understandable for all students, no matter their schooling or background.

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