Electrolysis of Aqueous Sodium Chloride
Electrolysis of Aqueous Sodium Chloride
Practical Skills Development
- Use of appropriate apparatus and techniques to draw, set up and use electrochemical cells for separation and production of elements and compounds
- Safe use of appropriate qualitative reagents and techniques to analyse and identify unknown samples or products including gas tests
- Presenting observations and other data using appropriate formats
Aim
- To electrolyse sodium chloride solution (brine) and identify the products at the electrodes
Health & Safety Aspects
Hazard symbols to show substances that are corrosive, toxic flammable and hazardous to the environment
- Safety glasses should be worn
- The products of this electrolysis are hazardous
- Sodium hydroxide produced is a corrosive substance
- The chlorine gas produced is toxic and harmful to the environment. The reaction should be carried out in a well ventilated area or fume cupboard
- The hydrogen gas produced is a flammable gas is produced so you should ensure there are no naked flames in proximity to the equipment
Electrolysis of aqueous solutions
Materials
- Electrolysis cell
- Retort stand, clamp & boss
- 0.5 mol /dm3 sodium chloride solution
- DC Power pack or battery packs
- Wires & crocodile clips
- Micro test tubes to collect gases
- Blue litmus paper
- Universal indicator solution
Method
- Set up the electrolysis cell and make sure it is secured to the stand with a clamp and boss
- Fill the cell with the sodium chloride solution
- Fill the micro tubes with sodium chloride solution and carefully invert them over each electrode to collect any gases given off
- Connect the wires and crocodile clips to the electrodes and power pack
- Turn on the current and run until the microtubes are filled with gas, then switch the power off
- Test the gases in the microtubes with a) a lighted splint and b) damp blue litmus paper
Remember:
- The negative terminal is the cathode (where cations migrate to)
- The positive terminal is the anode (where anions migrate to)
Results
Observations from the Electrolysis Experiment
Conclusions
- The gas produced at the cathode (negative electrode) burns with a squeaky pop, indicating hydrogen
- The gas at the anode initially turns the blue litmus red, indicating an acid, and is then bleached
- The gas is chlorine which dissolves in the water forming hydrochloric acid
- The universal indicator turns blue/purple indicating a strong alkali has been formed
- The solution is sodium hydroxide
- The indicator colour will often fade due to the bleaching action of the chlorine produced at the anode