Names & Formulae of Ionic Compounds (Edexcel GCSE Chemistry: Combined Science)

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Naming Ionic Compounds

  • Ionic compounds contain metal and non-metal elements joined together as particles called ions
  • The metal element’s symbol is always written first
  • The non-metal element always takes on the name ending ‘– ide’ unless oxygen is also present,
    • For example, PbS is called lead sulfide and MgCl2 is called magnesium chloride

  • When oxygen is present the name ending is usually ‘-ate’
    • For example, CuSO4 is copper sulfate, KClO3 is potassium chlorate and Na2CO3 is sodium carbonate

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Deducing Formulae

  • The formulae of simple ionic compounds can be calculated if you know the charge on the ions
  • Below are some common ions and their charges:

Common Ions & Their Charges Table

Formula _ Charge of Common Ions, downloadable IGCSE & GCSE Chemistry revision notes

  • For ionic compounds you have to balance the charge of each part by multiplying each ion until the sum of the charges = 0
  • Example: what is the formula of aluminium sulfate?
    • Write out the formulae of each ion, including their charges
    • Al3+ SO42-

  • Balance the charges by multiplying them out:

    Al3+ x 2 = +6 and SO42- x 3 = -6; so +6 – 6 = 0

  • So the formula is Al2(SO4)3

Examiner Tip

Another method that also works is to 'swap the numbers'. In the example above the numbers in front of the charges of the ions (3 and 2) are swapped over and become the multipliers in the formula (2 and 3). Easy when you know how!

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Stewart

Author: Stewart

Expertise: Chemistry Lead

Stewart has been an enthusiastic GCSE, IGCSE, A Level and IB teacher for more than 30 years in the UK as well as overseas, and has also been an examiner for IB and A Level. As a long-standing Head of Science, Stewart brings a wealth of experience to creating Exam Questions and revision materials for Save My Exams. Stewart specialises in Chemistry, but has also taught Physics and Environmental Systems and Societies.