Ionic Bonding (Edexcel GCSE Chemistry: Combined Science)

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Ionic Bonds

Sodium Chloride Dot & Cross Diagram

  • The process of ion formation does not happen in isolation; sodium atoms want to lose electrons and chlorine atoms want to gain electrons
  • We can use dot & cross diagram to show this as one continuous process
  • The positive and negative charges are held together by the strong electrostatic forces of attraction between oppositely charged ions
  • This is what holds ionic compounds together

Ionic bonding – Sodium Chloride, IGCSE & GCSE Chemistry revision notes

Sodium chloride ionic bonding

Magnesium Oxide Dot & Cross Diagram

  • Magnesium is a group 2 metal so will lose two outer electrons to another atom to have a full outer shell of electrons
    • A positive ion with the charge 2+ is formed

  • Oxygen is a group 6 non-metal so will need to gain two electrons to have a full outer shell of electrons
  • Two electrons will be transferred from the outer shell of the magnesium atom to the outer shell of the oxygen atom
  • The oxygen atom will gain the two electrons
    • A negative ion with charge 2- is formed

Magnesium Oxide dot & cross diagram, IGCSE & GCSE Chemistry revision notes

Diagram showing the dot-and-cross diagram of magnesium oxide

Examiner Tip

You should be able to draw dot & cross diagrams for combinations of ions from groups 1,2, 6 and 7.

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Ionic Lattices

  • Ionic compounds are made of charged particles called ions which form a giant lattice structure
  • A lattice is a regular repeating arrangement of particles, in this case, ions
  • Ionic substances have high melting and boiling points due to the presence of strong electrostatic forces acting between the oppositely charged ions
  • These forces act in all directions and a lot of energy is required to overcome themNaCl Lattice_ Ball + Ball & Stick, IGCSE & GCSE Chemistry revision notes

Strong electrostatic forces act in all directions in an ionic solid such as sodium chloride

Examiner Tip

Ions with higher charge have stronger electrostatic forces and will thus have higher melting and boiling points.

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Stewart

Author: Stewart

Expertise: Chemistry Lead

Stewart has been an enthusiastic GCSE, IGCSE, A Level and IB teacher for more than 30 years in the UK as well as overseas, and has also been an examiner for IB and A Level. As a long-standing Head of Science, Stewart brings a wealth of experience to creating Exam Questions and revision materials for Save My Exams. Stewart specialises in Chemistry, but has also taught Physics and Environmental Systems and Societies.