Combustion of Hydrocarbons (WJEC GCSE Chemistry)

Revision Note

Alexandra Brennan

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Combustion of Fuels

  • Fuels are substances that react with oxygen to release energy 
  • This reaction is called combustion 
    • Due to the release of energy, combustion reactions are exothermic 
  • When there is plenty of oxygen for the fuel to burn in, complete combustion occurs 
  • In complete combustion, all of the elements within the fuel react fully with the oxygen 
  • Many fuels, such as natural gas and petrol, consist of hydrocarbons 
    • A hydrocarbon is an compound containing hydrogen and carbon atoms only 
  • When the hydrocarbon undergoes complete combustion:
    • The carbon reacts with oxygen to form carbon dioxide, CO2
    • The hydrogen reacts with oxygen to form water, H2O

Summary table of complete combustion reactions

Fuel   Equation 
 Methane methane +  oxygen  →  carbon dioxide  +  water 
Ethane ethane +  oxygen  →  carbon dioxide  +  water 
Ethanol ethanol +  oxygen  →  carbon dioxide  +  water 

  • You might be asked to balance chemical equations for combustion reactions
  • The balanced symbol equation for the combustion of methane is:

CH4  +   2O2   →   CO2   +   2H2O  

  • To balance combustion equations, balance the carbon atoms first, then the hydrogen atoms and finally the oxygen atoms 

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Combustion is the burning of a fuel in oxygen

Worked example

Balance the symbol equation for the combustion of propane. 

___C3H8  +  ___O2 → ___CO2  +  ___H2O

Answer: 

  • Balance the carbon atoms first
    • There are 3 on the left hand side so place a 3 in front of carbon dioxide 
      • ___C3H8  +  ___O2 →  3CO2  +  ___H2O
  • The balance the hydrogen atoms 
    • There are 8 on the left hand side, so a 4 needs placing in front of water 
      • ___C3H8  +  ___O2 →  3CO2  4H2O
  • Finally, balance the oxygen atoms 
    • There are now 10 oxygen atoms on the right hand side (6 from carbon dioxide, and 4 from water)
    • A 5 needs placing in front of oxygen
      • ___C3H8  5O2 →  3CO2  4H2O

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Alexandra Brennan

Author: Alexandra Brennan

Expertise: Chemistry

Alex studied Biochemistry at Newcastle University before embarking upon a career in teaching. With nearly 10 years of teaching experience, Alex has had several roles including Chemistry/Science Teacher, Head of Science and Examiner for AQA and Edexcel. Alex’s passion for creating engaging content that enables students to succeed in exams drove her to pursue a career outside of the classroom at SME.