Testing for Sulfate Ions (WJEC GCSE Chemistry)
Revision Note
Test for Sulfates
Acidify the sample with dilute hydrochloric acid and then add a few drops of aqueous barium chloride
If a sulfate is present then a white precipitate of barium sulfate is formed:
Ba2+ (aq) + SO42- (aq) → BaSO4 (s)
The test can also be carried out with barium nitrate solution
Diagram to show the test for sulfate ions
A white precipitate of barium sulfate is a positive result for the presence of sulfate ions
Examiner Tips and Tricks
HCl is added first to remove any carbonates which may be present and would also produce a precipitate and interfere with the results.
This test can be carried out using nitric acid and barium nitrate. The barium ion from the nitrate will again form a white precipitate of barium sulfate.
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