Flame Tests (AQA GCSE Chemistry)

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Flame tests

  • The flame test is used to identify the positive metal ion (cations) by the colour of the flame they produce
    • Ions from different metals produce different colours
  • To carry out a flame test:
    • Dip the loop of an unreactive metal wire such as nichrome or platinum in dilute acid
    • Hold it in the blue flame of a Bunsen burner until there is no colour change
    • Dip the loop into the solid sample / solution and place it in the edge of the blue Bunsen flame
  • It is important to place the wire into acid first to prevent contamination
    • Not doing this might result in two or more ions being present on the wire meaning the colours will mix
    • One colour could mask another colour and you will not be able to identify the ion

Flame tests

Diagram showing how to carry out a flame test

The blue flame must be used to carry out a flame test 

  • The flame test colours can be seen below:
Metal ion Colour of flame 
Li+  crimson
Na+ yellow
K+ lilac
Ca2+ orange-red
Cu2+ green

Flame test colours

Diagram of flame colours for different metal ions

Metals form distinctive coloured flames

Examiner Tip

Make sure you are specific about the colour of the flame, for example, you must say calcium ions form an orange-red flame, not a red flame. 

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Stewart

Author: Stewart

Expertise: Chemistry Lead

Stewart has been an enthusiastic GCSE, IGCSE, A Level and IB teacher for more than 30 years in the UK as well as overseas, and has also been an examiner for IB and A Level. As a long-standing Head of Science, Stewart brings a wealth of experience to creating Exam Questions and revision materials for Save My Exams. Stewart specialises in Chemistry, but has also taught Physics and Environmental Systems and Societies.