Titration Calculations (AQA GCSE Chemistry): Revision Note
How to do titration calculations
Higher tier only
Once a titration is completed and the average titre has been calculated, you can now proceed to calculate the unknown variable using the formula triangle as shown below
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Formula triangle showing the relationship between concentration, number of moles and volume of liquid
Worked Example
25.00 cm3 of 0.15 mol/dm3 barium hydroxide, Ba(OH)2, was required to neutralise 12.80 cm3 of nitric acid, HNO3 , during a titration. Calculate the concentration of HNO3 that was used. Give your answer to 2 decimal places.
Ba(OH)2 (aq) + 2HNO3 (aq) → Ba(NO3)2 (aq) + 2H2O (l)
Answer:
Step 1: Calculate the number of moles of barium hydroxide
Moles of barium hydroxide = concentration x volume (dm3) = 0.15 x 0.025 = 3.75 x 10–3 mols
Step 2: Using the equation, calculate the number of moles of nitric acid
Moles of nitric acid = 3.75 x 10–3 x 2 = 7.5 x 10-3
The number of moles must be multiplied by 2 due to the 1:2 ratio
Step 3: Calculate the concentration of nitric acid
Concentration of nitric acid =
= 0.59 mol/dm3 to 2 dp
Remember to convert cm3 to dm3 by dividing by 1000
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