How to do titration calculations
Higher tier only
- Once a titration is completed and the average titre has been calculated, you can now proceed to calculate the unknown variable using the formula triangle as shown below
Formula triangle showing the relationship between concentration, number of moles and volume of liquid
Worked example
25.00 cm3 of 0.15 mol/dm3 barium hydroxide, Ba(OH)2, was required to neutralise 12.80 cm3 of nitric acid, HNO3 , during a titration. Calculate the concentration of HNO3 that was used. Give your answer to 2 decimal places.
Ba(OH)2 (aq) + 2HNO3 (aq) → Ba(NO3)2 (aq) + 2H2O (l)
Answer:
- Step 1: Calculate the number of moles of barium hydroxide
- Moles of barium hydroxide = concentration x volume (dm3) = 0.15 x 0.025 = 3.75 x 10–3 mols
- Step 2: Using the equation, calculate the number of moles of nitric acid
- Moles of nitric acid = 3.75 x 10–3 x 2 = 7.5 x 10-3
- The number of moles must be multiplied by 2 due to the 1:2 ratio
- Step 3: Calculate the concentration of nitric acid
- Concentration of nitric acid = = 0.59 mol/dm3 to 2 dp
- Remember to convert cm3 to dm3 by dividing by 1000