Giant Covalent Structures (AQA GCSE Chemistry)

Revision Note

Stewart Hird

Last updated

Giant covalent structures

  • Giant covalent structures are solids with high melting points

  • They have a huge number of non-metal atoms bonded to other non-metal atoms via strong covalent bonds

  • These structures can also be called giant lattices and have a fixed ratio of atoms in the overall structure

  • Three examples include diamond, graphite and silicon dioxide

Examiner Tips and Tricks

If you are unsure whether a covalent structure is a giant structure or consists of small molecules, think about whether it is a solid, liquid or gas at room temperature. Giant covalent structures are solids at room temperature, those consisting of small molecules are liquids and gases. 

Properties of giant covalent structures

  • Diamond, graphite and silicon dioxide all have giant covalent structures 

  • Diamond and graphite are made from carbon atoms 

  • Silicon dioxide (silica) is made from silicon and oxygen atoms

  • All giant covalent structures have high melting points because:

    • There are strong covalent bonds between atoms

    • These require lots of energy to overcome 

Giant covalent structures

Diagram showing three giant covalent structures; diamond, graphite and silicon dioxide

Diamond, graphite and silicon dioxide 

Examiner Tips and Tricks

Make sure you can recognise diamond, graphite and silicon dioxide from diagrams!

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Stewart Hird

Author: Stewart Hird

Expertise: Chemistry Lead

Stewart has been an enthusiastic GCSE, IGCSE, A Level and IB teacher for more than 30 years in the UK as well as overseas, and has also been an examiner for IB and A Level. As a long-standing Head of Science, Stewart brings a wealth of experience to creating Topic Questions and revision materials for Save My Exams. Stewart specialises in Chemistry, but has also taught Physics and Environmental Systems and Societies.