Ideal Gas Equation (DP IB Physics)
Revision Note
Ideal Gas Equation
The two ideal gas equations, derived from the empirical gas laws, are:
The variables will be outlined below
The empirical gas laws can be combined to give a single constant, known as the ideal gas constant, R
| Boyle's Law | Charles' Law | Pressure Law |
relationship | |||
constants |
An ideal gas is defined as:
A gas which obeys the ideal gas equation at all pressures, volumes and temperatures
Combining the gas laws leads to the ideal gas equation:
Where:
P = pressure (Pa)
V = volume (m3)
n = number of moles (mol)
R = 8.31 J K–1 mol–1 (ideal gas constant)
T = temperature (K)
Constants
The ideal gas constant R is the macroscopic equivalent of the Boltzmann constant
The ideal gas constant is associated with macroscopic quantities such as volume and temperature
The Boltzmann constant is associated with the thermal energy of microscopic particles
The Boltzmann constant is defined as the ratio of the ideal gas constant R and Avogadro's constant NA:
Recall from the Amount of Substance revision note that
This gives another form of the ideal gas equation:
Where:
N = number of molecules
kB = 1.38 × 10−23 J K−1 (Boltzmann constant)
Worked Example
A gas has a temperature of –55°C and a pressure of 0.5 MPa. It occupies a volume of 0.02 m3.
Calculate the number of gas particles.
Answer:
Step 1: Write down the known quantities
Temperature, T = –55°C = 218 K
Pressure, p = 0.5 MPa = 0.5 × 106 Pa
Volume, V = 0.02 m3
Step 2: Write down the equation of state of ideal gases
Step 3: Rearrange the above equation to calculate the number of moles n
Step 4: Substitute numbers into the equation
From the data booklet, R = 8.31 J K–1 mol–1
Step 5: Calculate the number of particles N
Examiner Tips and Tricks
The values for the gas constant, Avogadro constant and Boltzmann constant are all given in your data booklet.
Always make sure that temperature T is in kelvin for this topic. You must convert this from °C if not using the following conversion
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