Electric Potential Difference
- Potential difference (p.d.) is a measure of the electrical potential energy transferred by electrons as they move between two points in a conductor
- The definition of potential difference, also known as voltage, is:
The work done per unit charge on moving a positive charge between two points along the path of the current
- Potential difference is measured in volts (V) and is calculated as follows:
- Where:
- V = potential difference (V)
- W = work done (J)
- q = charge (C)
- From the above equation, one volt is equal to one joule per unit coulomb
- 1 V = 1 J C–1
- The potential difference in a d.c. circuit is provided by cells or batteries
- Each cell has a positive terminal (high potential location) and a negative terminal (low potential location)
- A battery is a collection of cells arranged positive terminal to negative terminal
A cell and a battery made of three cells
- When both terminals of a cell, or battery, are connected to a loop of conducting wire, a circuit is formed
- The cell or battery is the source of the potential difference needed for the electrons to flow
- Electrons gain electrical potential energy as they move through the cell
- A small amount of their energy is transferred to the metal ions in the wire
- The flow of electrons is from the negative to the positive terminal
The Electronvolt
- The energy values associated to electrons and other microscopic particles are very small when expressed in SI units
- For this reason, it is often more convenient to use another unit for energy - the electronvolt (eV)
- The electronvolt is defined as follows:
The amount of energy needed to move an electron through a potential difference of one volt
Worked example
Determine the value of 1 eV in joules (J).
Answer:
Step 1: Recall the definition of electronvolt
- One electronvolt is the work W associated with an electron of charge e moving through a potential difference V = 1V
- Where e is the charge of an electron = 1.6 × 10–19 C
Step 2: Substitute this and the value of the voltage into the above equation for W
W = (1.6 × 10–19 C) × 1 V
W = 1.6 × 10–19 J
- One electronvolt is equal to 1.6 × 10–19 joules
Examiner Tip
The value for the charge of an electron is given on your data sheet.
The units of electronvolt (eV) will appear in future topics such as a in Spectra & Atomic Energy Levels