Applications of Radioactivity
- When selecting a radioactive isotope for use in industry, agriculture or medicine, the key factors to consider are
- The penetrating power of the decay particle
- The half-life of the decay particle
- Some key examples which require the use of radioactive isotopes are:
- Nuclear power
- In medicine e.g. radiotherapy, tracers and sterilising equipment
- Carbon dating
- Uranium-lead dating for ageing rocks
- Detecting leaks in underground pipes
- Controlling the thickness of materials
- Smoke detectors
Carbon Dating
- The isotope carbon-14 is commonly used in radioactive dating
- It forms as a result of cosmic rays knocking out neutrons from nuclei, which then collide with nitrogen nuclei in the air:
- All living organisms absorb carbon-14, but after they die they do not absorb any more
- The proportion of carbon-14 is constant in living organisms as carbon is constantly being replaced during the period they are alive
- When they die, the activity of carbon-14 in the organic matter starts to fall, with a half-life of around 5730 years
- Samples of living material can be tested by comparing the current amount of carbon-14 in them and compared to the initial amount (which is based on the current ratio of carbon-14 to carbon-12), and hence they can be dated
Reliability of Carbon Dating
- Carbon dating is a highly reliable method for estimating the ages of samples between 500 and 60 000 years old
- This range can be explained by looking at the decay curve of carbon-14:
Carbon-14 decay curve used for radiocarbon dating
- If the sample is less than 500 years old:
- The activity of the sample will be too high to measure small changes accurately
- Therefore, the ratio of carbon-14 to carbon-12 will be too high to determine an accurate age
- If the sample is more than 60 000 years old:
- The activity will be too low to distinguish between changes in the sample and background radiation
- Therefore, the ratio of carbon-14 to carbon-12 will be too small to determine an accurate age
- Further sources of uncertainty arise with this dating method because:
- The level of production of carbon-14 in the atmosphere varies slightly with location
- The concentration of carbon-14 in the atmosphere may not have been constant over time
Uranium-Lead Dating
- For many years, scientists could not agree on the age of the Earth
- Until recently, the Earth was believed to be only millions of years old
- Over the last century, radiometric dating methods have enabled scientists to discover the age of the Earth is many billions of years old
- The most critical of these methods is uranium-lead dating
Uranium atoms decay whilst the number of lead atoms increases
- Initially, there is only uranium in the rock, but over time, the uranium decays via a decay chain which ends with lead-206, which is a stable isotope
- Uranium-238 has a half-life of 4.5 billion years
- Over time, the ratio of lead-206 atoms to uranium-238 atoms increases
- The ratio of uranium to lead in a sample of rock can then be used to determine its age
The decay chain of uranium-238 into lead-206 has been crucial for determining an accurate age of the Earth
Detecting Leaks in Underground Pipes
- Leaks in underground pipes can be detected by introducing a gamma emitter to the fluid supply in the pipe
- By moving a detector along the ground above the pipe, the location of the leak can be identified at the point where an increased count rate is detected
- Gamma radiation is required as it is the most penetrating type of radiation
- It is the only type of radiation that would be detectable after passing through several metres of ground
- Beta radiation could be used if the pipe is not too thick and is near the surface
- The half-life of the isotope must be
- Long enough for the activity of the source to remain at detectable levels
- Short enough that the isotope does not stay present in the supply any longer than required
- The isotope sodium-24 is often used in leak detection
- It emits both beta and gamma radiation and has a half-life of about 15 hours
The location of a leak in an underground pipe can be found at the point where a detector records a raised count rate compared to the other points along the pipe
Controlling the Thickness of Materials
- Beta radiation can be used to determine the thickness of aluminium foil, paper, plastic, and steel
- The thickness can be controlled by measuring how much beta radiation passes through the material to a Geiger counter
- Beta radiation must be used, because:
- Alpha particles would be absorbed by all the materials
- Gamma radiation would pass through undetected through the materials
- The Geiger counter controls the pressure of the rollers to maintain the correct thickness
- A source with a long half-life must be chosen so that it does not need to be replaced often
The pressure of the rollers can be adjusted to control the thickness of the aluminium foil depending on the amount of beta radiation detected
Smoke Detectors
- Smoke detectors contain a small amount of americium-241, an alpha emitter
- Within the detector, alpha particles are emitted and cause the ionisation of nitrogen and oxygen molecules in the air
- These ionised molecules enable the air to conduct electricity by allowing a small current can flow
- If smoke enters the alarm, it absorbs the alpha particles, hence reducing the current which causes the alarm to sound
- Americium-241 has a half-life of 460 years, so throughout the lifetime of a smoke detector, the activity of the source will not decrease significantly and it will not have to be replaced
The operation of a smoke detector
Worked example
Below are listed four radionuclides, together with the type of radiation they emit
Select the most suitable radionuclide in the following applications
(a) ANSWER: C
- Alpha and low energy beta radiation would most likely be absorbed by the bag
- Therefore, gamma radiation, or very high energy beta particles, would be needed to penetrate the bag
- This would be best suited to Cobalt-60
(b) ANSWER: D
- Static electricity is an imbalance of electric charges on the surface of the polythene and is generally composed of negatively charged electrons
- In order to get rid of the static charge, it will need to be neutralised
- Beta-plus particles, or positrons, are the antimatter counterpart of the electron, and hence, are oppositely charged
- When the positrons are directed at the surface of the polythene, the electrons will be attracted to them and become neutralised as the particles annihilate as they collide
- Therefore, the beta-plus emitter, Fluorine-18, would be best suited to this job
(c) ANSWER: B
- Alpha particles would not be suitable for measuring the thickness of metal as they can be stopped by a thin sheet of paper
- Gamma rays are the most penetrating of the radiations and hence would not be suitable where thickness monitoring is up to a few millimetres as they would all pass through
- Beta particles are ideally suited as they have enough energy to pass through thin sheets of metal and any changes in thickness would be easily detected
- Therefore, the beta-minus emitter Strontium-90 would be the most suitable isotope
(d) ANSWER: A
- Since smoke detectors are present inside homes and other buildings, they must pose no hazard to residents
- This means the smoke detector must contain a very small amount of the radioactive material
- Also, the radiation should not be too penetrating and should only be able to travel a few centimetres
- Therefore, an alpha source should be selected – this means Americium-241 would be the most suitable isotope