Syllabus Edition

First teaching 2024

First exams 2026

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Physical & Chemical Properties of Water (HL) (DP IB Environmental Systems & Societies (ESS))

Revision Note

Physical & Chemical Properties of Water

  • Water has some unique physical and chemical properties

  • These properties make water crucial to life on Earth

Polarity and hydrogen bonding

  • Water molecules are polar

    • This means they have a slight positive charge on one side (near the hydrogen atoms) and a slight negative charge on the other (near the oxygen atom)

  • This uneven distribution of charge is called polarity

    • Polarity allows water to form hydrogen bonds between its molecules

    • The slightly positive hydrogen atom in one water molecule is attracted to the slightly negative oxygen atom in another

    • This creates weak bonds between water molecules

    • Collectively, however, these bonds are strong enough to give water its unique properties

    Diagram of three water molecules showing hydrogen bonding. Oxygen atoms are red, hydrogen atoms are grey. Blue dotted lines represent hydrogen bonds.
    The polarity of water molecules allows hydrogen bonds to form between adjacent water molecules

Cohesion

  • Cohesion is the result of hydrogen bonding between water molecules

  • This makes water molecules 'stick' together, allowing it to form droplets and maintain surface tension

    • For example, water droplets form beads on a waxy surface, and insects like water striders (also known as pond skaters) can move across water without sinking

Adhesion

  • Adhesion occurs when water molecules stick to other materials

  • This can help water to move through narrow spaces

    • This is seen in capillary action, an import process occurring in the xylem during transpiration

    • This is where water moves up plant stems against gravity, which is essential in order for plants to transport water from their roots to their leaves

Diagram showing water molecules moving through xylem cells via cohesion and adhesion by hydrogen bonding, with detailed cell wall interactions.
Hydrogen bonding results in cohesion and adhesion forces in xylem which allows water molecules to flow through the plant in a continuous stream

Solvent properties

  • The polarity of water also makes it an effective solvent

    • This means it can dissolve many substances, especially salts and polar molecules

  • This ability is essential for life because it allows water to transport important substances like nutrients, minerals, and gases within living organisms

    • For example, in the human body, water dissolves salts, sugars, and proteins

    • This enables them to be carried in the bloodstream to cells

Transparency

  • Water is transparent, meaning light can pass through it

  • This transparency is essential for aquatic ecosystems because it allows sunlight to penetrate underwater

  • This enables photosynthesis in aquatic plants and algae, which support aquatic food webs

    • In lakes and oceans, the depth to which sunlight penetrates determines the zone where photosynthetic organisms can survive

High specific heat capacity

  • Water has a high specific heat capacity

    • This means it can absorb a large amount of heat energy without significantly increasing its temperature

  • This property allows water to regulate environmental and body temperatures, maintaining stable conditions for life

    • For example, oceans absorb heat from the sun during the day and release it slowly at night

      • This moderates coastal climates and prevents extreme temperature changes

    • This property is also essential in maintaining body temperature in animals, as water in blood helps distribute heat evenly

      • This prevents rapid overheating or cooling

Seal resting on snow-covered ice with speckled fur, against a background of scattered ice and water. The seal looks alert with its head slightly raised.
Artic and sub-artic species, such as the ringed seal (Pusa hispida) are able to survive throughout the year due to stable sea temperatures (photo by NOAA Seal Survey, Public domain, Wikimedia)

Density and temperature

  • Water has an unusual density pattern; it is most dense at 4 °C

  • As it cools below this temperature and freezes, water expands, making ice less dense than liquid water

    • This is why ice floats

  • This property is vital for life in cold environments

    • For some species, it provides a valuable habitat, e.g. the floating sea ice enables polar bears to hunt seals

  • Also, when ice forms on the surface of lakes or oceans, it acts as an insulating layer

  • This protects aquatic life by preventing the water below from freezing completely

    • Without this property, whole bodies of water could freeze solid in cold climates, disrupting ecosystems and killing many species

Gas solubility in water

  • Water can dissolve gases like oxygen and carbon dioxide

  • The solubility of these gases varies with temperature and pressure.

    • Cold water generally holds more dissolved oxygen than warm water

    • This is why cold aquatic environments can often support more life.

      • For example, the Arctic and Antarctic oceans, with their cold temperatures, support rich ecosystems due to the high oxygen levels in the water

    • When water gets too warm, its ability to hold oxygen decreases

      • This can lead to problems like oxygen depletion in warmer waters, causing "dead zones" where aquatic life struggles to survive

Examiner Tip

COhesion = water particles sticking to each other.

ADhesion = water particles sticking to other materials.

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Alistair Marjot

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Expertise: Biology & Environmental Systems and Societies

Alistair graduated from Oxford University with a degree in Biological Sciences. He has taught GCSE/IGCSE Biology, as well as Biology and Environmental Systems & Societies for the International Baccalaureate Diploma Programme. While teaching in Oxford, Alistair completed his MA Education as Head of Department for Environmental Systems & Societies. Alistair has continued to pursue his interests in ecology and environmental science, recently gaining an MSc in Wildlife Biology & Conservation with Edinburgh Napier University.

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