Syllabus Edition

First teaching 2014

Last exams 2024

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Practice Paper 1 (DP IB Chemistry: SL)

Practice Paper Questions

1
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1 mark

Which of these processes are endothermic?

I.  Condensing

II. Subliming

III. Melting

  • I and II only

  • I and III only

  • II and III only

  • I, II and III

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2
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1 mark

Ethanoic acid has the formula CH3COOH. How many carbon atoms are present in 0.1 mol of ethanoic acid?

  • 6.0 x 1022

  • 1.2 x 1023

  • 6.0 x 1023

  • 1.2 x 1024

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3
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A periodic table is needed for this question 

Excess aqueous cold sodium hydroxide is reacted with 0.10 mol of chlorine gas, Cl2. One of the products is a compound of sodium, oxygen and chlorine.

What mass of the product is formed?

  • 3.54 g

  • 7.44 g

  • 14.8 g

  • 26.6 g

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4
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A periodic table is needed for this question

Chicken eggs are made up of 5% by mass of egg shell. The average egg has a mass of 50 g.

Assume that chicken eggshell is pure calcium carbonate. 

How many complete chicken’s egg shells would need to neutralise 50 cm3 of 2.0 mol dm-3 ethanoic acid?

  • 4

  • 3

  • 2

  • 1

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5
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The phosphide ion,  begin mathsize 16px style straight P presubscript 15 space end presubscript presuperscript 32 space end presuperscript superscript 3 minus end superscript end style, is used in medicine as a radiotherapy treatment for some forms of cancer. 

What is the composition of the phosphide ion?

           

      protons     

    neutrons     

   electrons   

A

B

C

D

15

15

17

17

17

17

15

15

32

18

15

32

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6
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1 mark

Which statements correctly describe the distribution of mass and charge in the atom?

     1    

   the negative charge is concentrated in one area outside the nucleus         

     2

   the mass is concentrated inside the nucleus

     3

   the negative charge is spread around outside the nucleus

  • 1 and 3

  • 1 and 2

  • 2 and 3

  • 1, 2 and 3

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7
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1 mark

Which of the following statements describes first ionisation energy?

  • The energy required to remove one mole of electrons from one mole of gaseous atoms
  • The energy required to remove the outermost electron from each atom in one mole of gaseous atoms
  • The energy required to remove the outermost electron from each atom in one mole of atoms
  • The energy required to produce one mole of ions from one mole of gaseous atoms

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8
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1 mark

 The electronegativity of four elements are given below 

N = 3.0       H = 2.1       F = 4.0      P = 2.1      

 What is the correct order of polarity for the following compounds

  • PH3 < PF3 < NF3 < NH3

  • PH3 < PF3 < NH3 < NF3   

  • NF3 < NH3 < PH3 < PF3 

  • PH3 < NH3 < NF3 < PF3 

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9
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Which of the species shown below does not have resonance structures?

  • C6H6

  • CO32-

  • C2H4

  • O3

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10
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What is the strongest type of intermolecular force exhibited in the amino acid molecule serine?

Otne2dIl_q3_4-3_ib_sl_medium_mcq

  • London dispersion forces

  • Permanent dipole permanent dipole forces

  • Hydrogen bonding

  • Covalent bonding 

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11
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Which of the following molecules will have the highest boiling point?

  • CH3CH2CHO

  • CH3CH2CH2NH2

  • CH3CH2OCH3

  • CH3CH2CH2F

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12
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An experiment was carried out to determine the approximate value for the molar enthalpy change of neutralisation. 

75 cm3 of 3.00 mol dm–3 hydrochloric acid was placed in a polystyrene beaker of negligible heat capacity. Its temperature was recorded, and then 75 cm3 of
3.00 mol dm−3 potassium hydroxide at the same temperature was quickly added, and the solution stirred. 

The temperature rose by 14 °C. The resulting solution may be considered to have a specific heat capacity of 4.18 J g-1 K-1

Which calculation below is correct?

  • begin mathsize 14px style negative fraction numerator left parenthesis 75 space cross times space 4.18 space cross times space 14 right parenthesis over denominator left parenthesis 6.0 cross times 0.150 right parenthesis end fraction end styleJ mol-1

  • begin mathsize 14px style negative fraction numerator left parenthesis 150 space cross times space 4.18 space cross times space 14 right parenthesis over denominator left parenthesis 3.0 space cross times 0.075 right parenthesis end fraction end styleJ mol-1

  • begin mathsize 14px style negative fraction numerator left parenthesis 150 space cross times space 4.18 space cross times space 14 right parenthesis over denominator left parenthesis 3.0 space cross times 75.0 right parenthesis end fraction end styleJ mol-1

  • begin mathsize 14px style negative fraction numerator left parenthesis 75 space cross times space 4.18 space cross times space 287 right parenthesis over denominator left parenthesis 6.0 cross times space 0.150 right parenthesis end fraction end styleJ mol-1

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13
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The equations below show the formation of sulfur oxides from sulfur and oxygen. 

S(s) + O2(g) → SO2(g)                   begin mathsize 14px style increment H subscript f superscript ⦵ end style = –297 kJ mol–1 

S(s) + 1½O2(g) →SO3(g)               begin mathsize 14px style increment H subscript f superscript ⦵ end style = –395 kJ mol–1 

What is the enthalpy change of reaction,begin mathsize 14px style increment straight H to the power of ⦵ end style,of 2SO2(g) + O2(g) → 2SO3(g) in kJ mol–1?

  • (794 − 594)

  • (296 + 395)

  • (− 395 + 297)

  • (−790 + 594)

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14
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1 mark

The reaction pathway for a reversible reaction is shown below:q1_5-3_ib_sl_easy_mcq

Which statement is correct?

  • The activation energy of the reverse reaction is +90 kJ mol–1

  • The activation energy of the forward reaction is +20 kJ mol–1

  • The activation of the reverse reaction is +20 kJ mol–1

  • The enthalpy change of forwards reaction is - 70 kJ mol–1

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15
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1 mark

The diagram shows the skeletal formula of cyclobutane.
 q3_5-3_mcq_hard_ib-chemistry-sl

The enthalpy change of formation of cyclobutane is +75.1 kJ mol–1, and the enthalpy change of atomisation of graphite is +712 kJ mol–1.

The bond enthalpy of C–H is 414 kJ mol–1 and of H–H is 436 kJ mol–1.

What is the average bond enthalpy of the C–C bond in cyclobutane?

  • 712 blank minus 436 plus 2 left parenthesis 414 right parenthesis plus fraction numerator 75.1 over denominator 4 end fraction

  • 712 blank plus 436 minus 414 minus fraction numerator 75.1 over denominator 4 end fraction

  • 712 blank plus 436 minus 2 left parenthesis 414 right parenthesis minus fraction numerator 75.1 over denominator 4 end fraction

  • 712 blank plus 436 minus 2 left parenthesis 414 right parenthesis minus 75.1

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16
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The energies of the reactants, the products and the transition state of a reaction are shown in the reaction pathway diagram below.

rGbZAS69_9

Which expression correctly represents how to calculate the activation energy of the forward reaction?

  • E1 – E2

  • E2 – E1

  • E2 – E3

  • E3 – E2

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17
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1 mark

Bleach solution contains sodium chlorate (I) which naturally decomposes according to the equation below:

2NaClO (aq)  → 2NaCl (aq)  +  O2 (g)

The bleach decomposes faster as the temperature increases. A 100 cm3 sample of 10% bleach was heated to 40 degreeC and the amount of oxygen evolved was measured against time.

The experiment was repeated under the same conditions, but this time using a 100 cm3 sample of 20% bleach. If the first experiment produces the dotted line, which line is produced by the second experiment?

hard-6

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    18
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    1 mark

    The dissociation of gas X2Y4 into XY2 is represented in the equation below:

    X2Y4 (g)    2XY2 (g)         increment straight H to the power of empty set = +60 kJ mol-1 

    At constant pressure, if the temperature of the equilibrium mixture of the gases is increased, will the volume of the mixture increase or decrease and why?

    • the volume will increase, but only because of a shift of equilibrium towards the right 

    • the volume will increase, both because of a shift of equilibrium towards the right and also because of thermal expansion 

    • the volume will stay the same because any thermal expansion could be exactly counteracted by a shift of equilibrium towards the left

    • the volume will decrease because a shift of equilibrium towards the left would more than counteract any thermal expansion 

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    19
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    1 mark

    The following Kc values were obtained for a reaction carried out at different temperatures, T1 to T4.

    Temperature

    Kc value

    T1

    1 x 10-2

    T2

    1 x 101

    T3

    1

    T4

    1 x 102


    Which of the following gives the correct amount of products in the mixtures from least to most?

    • T1 T2 T3T4

    • T4 T3 T2T1

    • T4 T2 T3T1

    • T1 T3 T2T4

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    20
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    What role does each species play in the equilibrium below according to Brønsted-Lowry theory?

    CH3COOH + HCl  ⇌ CH3COOH2+ + Cl-

     

    CH3COOH

    HCl

    CH3COOH2+

    Cl-

    A

    acid

    base

    base

    acid

    B

    acid

    base

    acid

    base

    C

    base

    acid

    base

    acid

    D

    base

    acid

    acid

    base

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      21
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      1 mark

      Four 1.0 M solutions of HCl, NH3, NaOH and CH3COOH have been mislabelled, but a student has a pH meter to test the pH of the solutions. Arrange the solutions in order of increasing pH:

      • HCl (aq) < NH3 (aq) < NaOH (aq) < CH3COOH (aq)

      • CH3COOH (aq) < HCl (aq) < NH3 (aq) < NaOH (aq)

      • HCl (aq) < CH3COOH (aq) < NH3 (aq) < NaOH (aq)

      • NaOH (aq) < NH3 (aq) < CH3COOH (aq) < HCl (aq)

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      22
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      1 mark

      The pH of clean rain water is around 5.5. Which substance is responsible for this?

      • Methane

      • Carbon dioxide

      • Nitrogen oxides

      • Sulfur dioxide

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      23
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      1 mark

      Which row correctly describes oxidation and reduction in terms of the transfer of electrons and changes in oxidation state? 

       

      Transfer of electrons

      Change in oxidation state

       

      oxidation

      reduction

      oxidation

      reduction

      A

      B

      C

      D

      gain

      loss

      loss

      gain

      loss

      gain

      gain

      loss

      increase

      increase

      decrease

      decrease

      decrease

      decrease

      increase

      increase

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        24
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        1 mark

        What is formed at the electrodes during the electrolysis of molten potassium iodide? 

         

        Positive electrode

        Negative electrode

        A

        K+

        I-

        B

        K

        I2

        C

        I-

        K+

        D

        I2

        K

         

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          25
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          1 mark

          Which features about the members of a homologous series are correct?

          1.  all members have the same general formula
          2.  the members have similar chemical properties
          3.  the members show a gradual change in physical properties
          • I and II only

          • I and III only

          • II and III only

          • I, II and III

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          26
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          1 mark

          What is the correct IUPAC name for the molecule shown?

          10-1-h-q4-mcqs-ib-chemistry

          • ethoxyethane

          • methoxyethane

          • propanone

          • propanal

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          27
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          1 mark

          In the hydrolysis of bromoethane by aqueous sodium hydroxide, what is the nature of the attacking group and of the leaving group?

           

           

          attacking group

          leaving group

          A

          B

          C

          D

          electrophile

          electrophile

          nucleophile

          nucleophile

          electrophile

          nucleophile

          electrophile

          nucleophile

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            28
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            A periodic table is needed for this question

            Which compound has an Mr of 84.18 and will react with HBr to give a product with an Mr of 165.09?10-2-h-q3-ib-chemistry-mcqs

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              29
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              1 mark

              Bromine exists as two isotopes 79Br and 81Br, which are found in almost equal abundance. 

              Which of the following statements is correct?

              • 79Br is more reactive than 81Br

              • The mass spectrum of C3H7Br has two molecular ion peaks at 122 and 124

              • The atomic radius of 79Br is less than the atomic radius of 81Br

              • The first ionisation energy of 79Br is less than the first ionisation energy of 81Br

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              30
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              1 mark

              Which alcohol is likely to have a fragment ion at m/e = 31 in its mass spectrum?

              • (CH3)2CHCH2OH

              • CH3CH(OH)CH2CH2CH3

              • CH3CH2CH2C(OH)(CH3)2

              • CH3CH2CH(OH)CH3

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