Atom Economy (DP IB Chemistry)
Revision Note
Atom Economy
The atom economy of a reaction shows how many of the atoms used in the reaction become the desired product
The rest of the atoms or mass is wasted
It is found directly from the balanced equation by calculating the Mr of the desired product
In addition reactions, the atom economy will always be 100%, because all of the atoms are used to make the desired product
Whenever there is only one product, the atom economy will always be 100%
For example, in the reaction between ethene and bromine:
CH2=CH2 + Br2 → CH2BrCH2Br
The atom economy could also be calculated using mass, instead or Mr
In this case, you would divide the mass of the desired product formed by the total mass of all reactants, and then multiply by 100
Efficient processes have high atom economies and are important to sustainable development
They use fewer resources
Create less waste
As well as atom economy and percentage yield there are other factors that can be used to gauge the efficiency of a chemical process
Rate
Quantities of reagents such as catalysts and solvents
Energy uses
Economic efficiency
Worked Example
Ethanol can be produced by various reactions, such as:
Hydration of ethene: C2H4 + H2O → C2H5OH
Substitution of bromoethane: C2H5Br + NaOH → C2H5OH + NaBr
Explain which reaction has a higher atom economy.
Answer:
Hydration of ethene has a higher atom economy (of 100%) because all of the reactants are converted into products, whereas the substitution of bromoethane produces NaBr as a waste product
Worked Example
Quantitative atom economy
The blast furnace uses carbon monoxide to reduce iron(III) oxide to iron.
Fe2O3 + 3CO → 2Fe + 3CO2
Calculate the atom economy for this reaction, assuming that iron is the desired product.
(Ar / Mr data: Fe2O3 = 159.6, CO = 28.0, Fe = 55.8, CO2 = 44.0)
Answer:
Step 1: Write the equation:
Step 2: Substitute values and evaluate:
Examiner Tips and Tricks
Careful: Sometimes a question may ask you to show your working when calculating atom economy.
In this case, even if it is an addition reaction and it is obvious that the atom economy is 100%, you will still need to show your working.
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