Syllabus Edition

First teaching 2023

First exams 2025

|

The Covalent Model (SL IB Chemistry)

Exam Questions

7 hours108 questions
11 mark

Silver and iodine are both shiny crystalline solids.

Which forces exist between neighbouring iodine molecules in solid iodine and particles in solid silver?

 

iodine

silver

A

metallic bonds

covalent bonds

B

ionic bonds

metallic

C

covalent bonds

covalent bonds

D

London dispersion forces

metallic

    Did this page help you?

    21 mark

    Which of these atoms is most electronegative?

    • Cl

    • Mg

    • Br

    • Na

    Did this page help you?

    31 mark

    Based on their Pauling electronegativity values, which atom is more likely to form a covalent bond with fluorine?

     

    atom

    Pauling value

     

    fluorine

    4.0

    A

    hydrogen

    2.2

    B

    copper

    1.9

    C

    magnesium

    1.3

    D

    potassium

    0.8

      Did this page help you?

      41 mark

      Hydrazine, N2H4, is a precursor for multiple pharmaceutical compounds. 

      Which of the diagrams below illustrate the most likely structure and bond angle of hydrazine?

      ma1_14-2_ib_sl_mcq_easy

        Did this page help you?

        51 mark

        Graphite has a structure containing layers of carbon atoms in hexagonal rings.

        Why is graphite a good conductor of electricity?

        • It has delocalised ions which can move and carry charge

        • It has delocalised electrons which are mobile

        • There are only weak London forces between the layers

        • Each carbon atom in the layers has only three covalent bonds

        Did this page help you?

        61 mark

        What is the correct bond angle in a trigonal planar molecule?

        • 107°

        • 120°

        • 180°

        • 109.5°

        Did this page help you?

        71 mark

        Which statement about the physical properties of substances is correct?

        • Covalent structures always have high melting points

        • Metals only conduct electricity when solid

        • Metals always have high melting points 

        • Ionic substances conduct electricity when liquid 

        Did this page help you?

        81 mark

        Which of the following statements about graphite is correct?

        • The bond angle in graphite is 109.5 o

        • There are only London forces between the layers of graphite

        • Graphite has a higher melting point than diamond

        • Graphite is soluble in water

        Did this page help you?

        91 mark

        Which substance is described in the table below?

        Melting point

        Electrical Conductivity

        Solubility

        Very high

        Non-conductor

        Does not dissolve

        • Silicon dioxide

        • Buckminsterfullerene

        • Graphite

        • Sodium chloride 

        Did this page help you?

        101 mark

        Which of the following is the correct resonance hybrid structure of the carbonate ion, CO32-?

        q8_14-2_ib_sl_easy_mcq

          Did this page help you?

          111 mark

          Which of the following dipole labels are not correct?q1_4-3_ib_sl_easy_mcq

            Did this page help you?

            121 mark

            Which of the following compounds is polar?

            • CCl4

            • BF3

            • PH3

            • CH3CH3

            Did this page help you?

            131 mark

            Which of the following statements is not correct?

            • The strongest type of intermolecular force in ammonia is hydrogen bonding

            • The strongest type of intermolecular force in water is hydrogen bonding

            • The strongest type of intermolecular force in hydrogen chloride is permanent dipole 

            • The strongest type of intermolecular forces in ethanol is permanent dipole 

            Did this page help you?

            141 mark

            Which of the following statements about ethylamine, CH3CH2NH2, is correct?

            • The strongest type of intermolecular force are London dispersion forces

            • The nitrogen atom does not have a lone pair present

            • The strongest type of intermolecular force is permanent dipole permanent dipole forces

            • The strongest type of intermolecular force is hydrogen bonding

            Did this page help you?

            151 mark

            Which of the following statements about butane, CH3CH2CH2CH3, and propanone, CH3COCH3 are correct? 

            1. The boiling point of propanone is higher than butane
            2. The boiling point of butane is higher than propanone
            3. The strongest type of intermolecular force in propanone are permanent dipole permanent dipole forces
            • I and II only

            • I and III only

            • II and III only

            • I, II and III

            Did this page help you?

            16
            Sme Calculator
            1 mark

            Which element does not form stable compounds that break the octet rule?

            • Sulfur

            • Oxygen

            • Boron

            • Chlorine

            Did this page help you?

            17
            Sme Calculator
            1 mark

            What are the bond angles in a molecule with five electron domains, XY5?

              Axial bond angles / o Equatorial bond angles / o
            A. 90 90
            B. 120 90
            C. 90 120
            D. 120 120

              Did this page help you?

              18
              Sme Calculator
              1 mark

              Which compound contains delocalised electrons?

              • Cyclohexane, C6H12

              • Cyclohexene, C6H10

              • Benzene, C6H6

              • Cyclohexanol, C6H11OH

              Did this page help you?

              19
              Sme Calculator
              1 mark

              Which structure does not show resonance?

              • Carbonate ion, CO32-

              • Hydroxide ion, OH-

              • Ethanoate ion, CH3COO-

              • Nitrate ion, NO3-

              Did this page help you?

              11 mark

              Which of the following statements about 2-methylpropan-2-ol, CH3C(CH3)(OH)CH3, are correct ? 

              1. The structure contains 16 bonding pair of electrons
              2. The O-C-C bond angle is 109.5 o
              3. The total number of electrons is 32
              • I and II only 

              • I and III only 

              • II and III only 

              • I, II and III

              Did this page help you?

              21 mark

              Which of the following molecules has the biggest overall dipole?

              q2_4-1_medium_mcq_ib-chemistry-hl

                Did this page help you?

                31 mark

                 The electronegativity of four elements are given below 

                N = 3.0       H = 2.1       F = 4.0      P = 2.1      

                 What is the correct order of polarity for the following compounds

                • PH3 < PF3 < NF3 < NH3

                • PH3 < PF3 < NH3 < NF3   

                • NF3 < NH3 < PH3 < PF3 

                • PH3 < NH3 < NF3 < PF3 

                Did this page help you?

                41 mark

                Below are four molecules. Which is the most polar molecule present?

                • CH3NH2

                • CH4

                • CCl4

                • CO2

                Did this page help you?

                51 mark

                The correct order of increasing boiling points for the following compounds is

                • 1-chlorobutane < butane < butan-1-ol 

                • Butan-1-ol < 1-chlorobutane < butane, 

                • Butane < 1-chlorobutane < butan-1-ol 

                • Butan-1-ol < butane < 1-chlorobutane 

                Did this page help you?

                61 mark

                What is the strongest type of intermolecular force exhibited in the amino acid molecule serine?

                Otne2dIl_q3_4-3_ib_sl_medium_mcq

                • London dispersion forces

                • Permanent dipole permanent dipole forces

                • Hydrogen bonding

                • Covalent bonding 

                Did this page help you?

                71 mark

                Hexane, C6H14 and 2,2-dimethylbutane, CH3C(CH3)2CH2CH3, are two isomers of one another and have the same Mr of 86.0. 

                Hexane has a higher boiling point than 2,2-dimethylbutane. 

                Which of the following statements is not correct?

                • hexane has a higher boiling point because it is a straight chain molecule

                • 2,2-dimethylbutane has a lower boiling point as it is a branched molecule 

                • 2,2-dimethylbutane only contains London dispersion forces 

                • hexane contains permanent dipole permanent dipole forces

                Did this page help you?

                81 mark

                Which of the following statements about propanal and propanone are correct?

                q6_4-3_ib_sl_medium_mcq

                1. The strongest type of intermolecular force in both molecules is hydrogen bonding
                2. The strongest type of intermolecular force in both molecules is permanent dipole permanent dipole forces
                3. Both compounds are soluble in water

                • I and II only

                • I and III only

                • II and III only

                • I, II and III

                Did this page help you?

                91 mark

                Which molecule has the lowest boiling point?

                • CH3CH2CHO

                • CH3CH2CH2Cl

                • CH3CH2CH3

                • CH3CH2COOH

                Did this page help you?

                101 mark

                Boron trifluoride, BF3, reacts with trimethylamine, (CH3)3N, to form a compound of formula (CH3)3N.BF3

                How may this reaction be written using 3D structures to show  the shapes of the reactants and products?q2-1_14-2_ib_sl_medium_mcq

                Did this page help you?

                111 mark

                Which of the following statements about graphite are correct? 

                1.    The carbon atoms are joined together by three covalent bonds
                2.    Graphite contains delocalised electrons
                3.    The C-C-C bond angle is 109.5o
                • I and II only

                • I and III only

                • II and III only

                • I, II and III

                Did this page help you?

                121 mark

                Which statement below shows the correct information about diamond and silicon?

                • Diamond is macromolecular and silicon is simple molecular

                • The bond angles in the two structures are the same

                • The bond lengths are longer in C-C than in Si-Si

                • Diamond and silicon both conduct electricity due to delocalised electrons in their structure

                Did this page help you?

                131 mark

                Which one of these species has a bond angle of 120°?

                • H3O+  

                • TlBr32-

                • BCl3

                • NH3 

                Did this page help you?

                141 mark

                Which of the following statements about silicon dioxide is correct? 

                1.    Silicon dioxide forms a giant covalent network
                2.    Each silicon atom is covalently bonded to four oxygen atoms
                3.    Silicon dioxide molecules are V-shaped
                • I and II only

                • I and III only

                • II and III only

                • I, II and III

                Did this page help you?

                151 mark

                Ibuprofen is an anti-inflammatory drug that is used for treating pain, fever and inflammation. The structure is shown below.q8_4-2_ib_sl_medium_mcq 

                Ibuprofen

                 What are the correct bond angles for a and b?

                 

                a

                b

                A

                120o

                120o

                B

                107o

                109.5o

                C

                109.5o

                120o

                D

                120o

                109.5o

                  Did this page help you?

                  161 mark

                  Which of the following molecules obeys the octet rule?

                  • BF3

                  • HCN

                  • BeCl2

                  • CS2

                  Did this page help you?

                  171 mark

                  Dichlorodifluoromethane, CCl2F2, has been used in aerosol propellants and as a refrigerant.

                  Which statement helps to explain why dichlorodifluoromethane is chemically inert?

                   

                  • the carbon-fluorine bond energy is large

                  • the carbon-fluorine bond has a low polarity

                  • fluorine is highly electronegative

                  • fluorine compounds are non-flammable

                  Did this page help you?

                  181 mark

                  Which species breaks the octet rule?

                  • PCl3

                  • BF4-

                  • SCl4

                  • NH4+

                  Did this page help you?

                  191 mark

                  Which combination correctly describes the geometry of BrF4- ?

                   

                  Electron domain geometry around Br

                  Molecular geometry around Br

                  A

                  Octahedral

                  Tetrahedral

                  B

                  Tetrahedral

                  Square planar

                  C

                  Octahedral

                  Square planar

                  D

                  Tetrahedral

                  Tetrahedral

                    Did this page help you?

                    201 mark

                    Which species contain delocalised electrons?

                    q1_14-2_ib_hl_medium_mcq

                    • I and II only

                    • I and III only

                    • II and III only 

                    • I, II and III

                    Did this page help you?

                    11 mark

                    CHCl3 and Br2 are both liquids at room temperature due to the existence of dipoles.

                    What dipoles are involved within CHCl3 and Br2?

                     

                    CHCl3

                    Br2

                    A

                    induced dipoles only

                    induced dipoles only

                    B

                    induced dipoles only

                    induced dipoles and permanent dipoles

                    C

                    induced dipoles and permanent dipoles

                    induced dipoles and permanent dipoles

                    D

                    induced dipoles and permanent dipoles

                    induced dipoles only

                      Did this page help you?

                      21 mark

                      Which of the following statements about 2-chloropropene, CH2C(Cl)CH3 is not correct

                      • There are 3 lone pairs in the molecule

                      • There are 24 valence electrons in the molecule 

                      • The molecule does obey the octet rule

                      • The molecule does not obey the octet rule

                      Did this page help you?

                      31 mark

                      Which of the following structures do not obey the octet rule?

                      1. BeCl2
                      2. BF3
                      3. H2O
                      • I and II only

                      • I and III only

                      • II and III only

                      • I, II and III

                      Did this page help you?

                      41 mark

                      Which is the shortest bond length in the following gases?

                      • oxygen-oxygen in oxygen gas, O2

                      • carbon-carbon in ethyne gas, C2H2

                      • nitrogen-nitrogen in nitrogen gas, N2

                      • oxygen-oxygen in ozone gas, O3

                      Did this page help you?

                      51 mark

                      Which statement best describes the intramolecular bonding in a carbonate ion, CO32-?

                      • Only London forces

                      • Electrostatic attraction between pairs of electrons and positively charged nuclei

                      • Permanent dipole permanent dipole forces

                      • Electrostatic attraction between separate carbonate ions

                      Did this page help you?

                      61 mark

                      The number of electrons in the valence shell of elements X and Y are 5 and 7 respectively. What is the formula and type of compound formed from these elements?

                      • Covalent, XY3

                      • Ionic, XY3

                      • Covalent, X3Y

                      • Ionic, X3Y

                      Did this page help you?

                      71 mark

                      In which series of compounds does covalent character increase when going from left to right?

                      • KI, KBr, KCl

                      • NaI, KI, RbI

                      • NaCl, MgCl2, AlCl3

                      • SO2, P4O10, SiO2

                      Did this page help you?

                      81 mark

                      Which of the following molecules will have the highest boiling point?

                      • CH3CH2CHO

                      • CH3CH2CH2NH2

                      • CH3CH2OCH3

                      • CH3CH2CH2F

                      Did this page help you?

                      91 mark

                      What is the correct order of boiling points for the following molecules, from lowest to highest?

                      • CH3F < F2 < CH3CH2F < HF

                      • F2 < CH3F < CH3CH2F < HF

                      • F2 < CH3CH2F < CH3F < HF

                      • HF < CH3CH2F <C H3F < F2  

                      Did this page help you?

                      101 mark

                      In which of the following processes do hydrogen bonds get broken?

                      • 2HBr (g) → H2 (g) + Br2 (g)

                      • C2H6 (l) → 2C (g) + 6H (g)

                      • H2 (l) → H2 (g)

                      • NH3 (l) → NH3 (g) 

                      Did this page help you?

                      111 mark

                      Hydrogen bonding occurs between molecules of propanal, CH3CH2CHO, and molecules of liquid Y. Which of the following is most likely to be liquid Y?

                      • CH3CO2CH3

                      • CH3OH

                      • CH3COCH3

                      • CH3CHO

                      Did this page help you?

                      121 mark

                      The following statements are all correct. Which of the statements can be explained, in part, by hydrogen bonding?

                      1. Ice is less dense than water
                      2. Butanone has a lower boiling point than butan-1-ol
                      3. At room temperature butanone can mix with water
                      • I and II only

                      • I and III only

                      • II and III only

                      • I, II and III

                      Did this page help you?

                      131 mark

                      Hydrogen bonding can occur between propanal, CH3CH2CHO and which other molecule?

                      • CH3COOH

                      • CH3CO2CH3

                      • CH3CH2F

                      • CH3COCH3

                      Did this page help you?

                      141 mark

                      Which of the following about dimethylamine, NH(CH3)2 , is correct?

                       

                      Bond angle

                      Strongest type of intermolecular force present

                      A

                      109.5

                      Permanent dipole permanent dipole forces

                      B

                      109.5

                      London dispersion forces

                      C

                      107o

                      Hydrogen bonding

                      D

                      105o

                      Hydrogen bonding

                        Did this page help you?

                        151 mark

                        Which of the following statements are correct? 

                        1. The strongest type of intermolecular force between BF3 molecules are permanent dipole permanent dipole forces
                        2. The strongest type of intermolecular force between HCN molecules are permanent dipole permanent dipole forces
                        3. The bond angle in HCN is larger than the bond angle in BF3
                        • I and II only

                        • I and III only

                        • II and III only

                        • I, II and III

                        Did this page help you?

                        161 mark

                        Which of the species shown below does not have resonance structures?

                        • C6H6

                        • CO32-

                        • C2H4

                        • O3

                        Did this page help you?

                        171 mark

                        Below are statements about the structure and bonding in silicon dioxide. Which pair of statements is correct?

                         

                        structure

                        bonding

                        A

                        silicon dioxide molecules are bent linear

                        silicon atoms have covalent bonds to two oxygen atoms

                        B

                        silicon dioxide has a giant macromolecular structure

                        each oxygen bonds covalently to one silicon atom

                        C

                        silicon dioxide has a giant macromolecular structure

                        silicon atoms bond to four oxygen atoms

                        D

                        silicon dioxide molecules are linear

                        silicon and oxygen atoms are joined by a double covalent bond

                          Did this page help you?

                          181 mark

                          Which compounds have an ionic lattice structure in the solid state?

                          1.   silicon dioxide
                          2.   sodium iodide
                          3.   ammonium sulfate
                          • I and II only

                          • I and III only

                          • II and III only

                          • I, II and III

                          Did this page help you?

                          191 mark

                          The correct shape and bond angle for the TlBr32- ion?

                           

                          Shape

                          Bond angle

                          A

                          Pyramidal

                          120°

                          B

                          Pyramidal

                          107°

                          C

                          Tetrahedral

                          109.5°

                          D

                          Tetrahedral

                          120°

                            Did this page help you?

                            201 mark

                            Which of the following is correct for the molecules of BeCl2 and BeCl42-?

                             

                            BeCl2

                            BeCl42-

                             

                            Shape

                            Bond angle

                            Shape

                            Bond angle

                            A

                            Linear

                            109.5°

                            Square planar

                            90°

                            B

                            V-shaped

                            107°

                            Square planar

                            90°

                            C

                            V-shaped

                            105°

                            Tetrahedral

                            109.5°

                            D

                            Linear

                            180°

                            Tetrahedral

                            109.5°

                              Did this page help you?

                              211 mark

                              Tramadol is an example of a painkiller which is classed as an opioid analgesic. It binds to opioid receptors in the central nervous system and inhibits noradrenaline and serotonin reuptake inhibiting pain transmission 

                              The structure is shown below 

                              Which of the following are the correct bond angles for a, b and c?

                              q8_4-2_ib_sl_hard_mcq

                               

                              a

                              b

                              c

                              A

                              120o

                              109.5o

                              107o

                              B

                              120o

                              107o

                              105o

                              C

                              107o

                              109.5o

                              107o

                              D

                              109.5o

                              107o

                              105o

                                Did this page help you?

                                221 mark

                                Some properties of substance X are given in the following table 

                                Melting Point

                                Very high

                                Strength

                                Very strong across the layer

                                Conductivity

                                Excellent conductor

                                Example of a Use

                                Used as a coating for smartphones, tablets and computers

                                What is a possible identity of substance X?

                                • Graphene

                                • Graphite

                                • Silicon dioxide 

                                • Buckminsterfullerene

                                Did this page help you?

                                231 mark

                                Sulfur forms the compound S4N4 with nitrogen, the structure is shown below.q10_4-2_ib_sl_hard_mcq

                                  Which of the following statements about S4N4 is correct?

                                • The sulfur atom marked x has two lone pairs

                                • The sulfur atom marked y has two lone pairs

                                • Each N atom has two lone pairs 

                                • The N-S-N bond angle will be larger than S=N=S bond angle 

                                Did this page help you?

                                241 mark

                                Nitrous acid is produced when nitrogen dioxide dissolves in water to produce acid rain. What is the correct Lewis structure for nitrous acid?

                                q3-8-3-mcq-hard-ib-chemistry-sl

                                  Did this page help you?

                                  25
                                  Sme Calculator
                                  1 mark

                                  Which of the following species is polar?

                                  • ICl4-

                                  • PF5

                                  • SO3

                                  • SH2

                                  Did this page help you?

                                  26
                                  Sme Calculator
                                  1 mark

                                  Which species can be represented with only one Lewis structure?

                                  • H2PO4-

                                  • O3

                                  • CH3COCH3

                                  • 1,3 cyclohexadiene

                                  Did this page help you?

                                  27
                                  Sme Calculator
                                  1 mark

                                  In which group do both compounds contain delocalised electrons?

                                  • K2CO3 and cyclohexene, C6H10

                                  • KOH and methybenzene, C7H8

                                  • KHCO3 and buta-1,3-diene, C4H6

                                  • Methanol and sodium methanoate, HCOONa

                                  Did this page help you?

                                  281 mark

                                  Which row of the table is correct about the trend and explanation in the boiling points of the alcohols CH3OH, C2H5OH and C3H7OH?



                                              

                                               Trend in boiling points                    

                                                                         Explanation                                                      

                                      A

                                  CH3OH >C2H5OH > C3H7OH 

                                  The London dispersion forces decrease with each additional CH2

                                  B

                                  CH3OH >C2H5OH > C3H7OH 

                                  The strength of the hydrogen bonds decreases with each additional CH2

                                  C

                                  C3H7OH >C2H5OH >CH3OH   

                                  The London dispersion forces increase with each additional CH2

                                  D

                                  C3H7OH >C2H5OH >CH3OH  

                                  The strength of the hydrogen bonds increases with each additional CH2

                                    Did this page help you?