Syllabus Edition

First teaching 2023

First exams 2025

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Practice Paper 1A (SL IB Chemistry)

Practice Paper Questions

11 mark

Which equation does not represent sublimation or deposition?

  • NH3 (g) + HCl (g) → NH4Cl (s)

  • I2 (s) → I2 (g)

  • C16H10O (s) → C16H10O (g) 

  • H2O (g) → H2O (s)

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21 mark

The atomic number of an element gives the number of protons in the nucleus which is also equal to the number of electrons. Which statement explains why atoms are neutral?

  • one proton has a mass 1840 times greater than one electron

  • the charge on an electron is equal and opposite to the charge on a proton

  • the difference in charge between electrons and protons is balanced by the neutrons

  • electrons are spread out in shells around the nucleus while protons are concentrated inside the nucleus

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31 mark

What is the correct sequence for the orbitals shown in an atom of vanadium in order of decreasing energy?

  • 3s 3p 4s 3d

  • 4s 3d 3s 3p

  • 4s 3d 3p 3s

  • 3d 4s 3p 3s

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41 mark

A hydrated carbonate of an unknown Group 1 metal has the formula X2CO310H2O and is found to have a relative formula mass of 286.19                              

What is the Group 1 metal?

  • Rb

  • K

  • Na

  • Li

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51 mark

The ideal gas equation below summarises the gas laws.

pV = nRT

Which statement below is correct?

  • there exist intermolecular forces of attraction between gas molecules  

  • ideal gas molecules will collide inelastically upon impact with each other 

  • one mole of an ideal gas occupies the same volume under the same conditions of temperature and pressure 

  • the volume of a given mass of an ideal gas is doubled if its temperature is raised from 25oC to 50o

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61 mark

Aluminium iodide, Al2I6 is a dimer and exists as a solid at room temperature. When it is a vapour it can exist as an AlI3 molecule. 

How many valence electrons are in an aluminium iodide, AlI3, molecule?

  • 22

  • 24

  • 26

  • 28

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71 mark

Below are four molecules. Which is the most polar molecule present?

  • CH3NH2

  • CH4

  • CCl4

  • CO2

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81 mark

Which of the following metals will have the greatest ability to conduct electricity?

  • Li

  • Mg

  • Na

  • Al

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9
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1 mark

A compound has an empirical formula of C2H6O and a molar mass of 92.16.

What is the molecular formula of this compound?

  • C2H6O 

  • C4H12O2

  • C6H18O3

  • C8H24O4

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101 mark

The correct order of increasing boiling points for the following compounds is

  • 1-chlorobutane < butane < butan-1-ol 

  • Butan-1-ol < 1-chlorobutane < butane, 

  • Butane < 1-chlorobutane < butan-1-ol 

  • Butan-1-ol < butane < 1-chlorobutane 

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111 mark

The properties of alloys can be explained in terms of metals having

  1. Non-directional bonding
  2. Delocalised electrons
  3. Ions of different size
  • I and II only

  • I and III only

  • II and III only

  • I, II and III

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121 mark

Which features about the members of a homologous series are correct?

  1.  all members have the same general formul
  2.  the members have similar chemical properties
  3.  the members show a gradual change in physical properties
  • I and II only

  • I and III only

  • II and III only

  • I, II and III

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131 mark

Which of the following statements is true as you move down Group I?

  • The first ionisation energy increases

  • The atomic radius increases

  • The melting point increases

  • The reaction with water becomes less vigorous

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141 mark

What is the correct IUPAC name for the molecule shown?

10-1-h-q4-mcqs-ib-chemistry

  • ethoxyethane

  • methoxyethane

  • propanone

  • propanal

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151 mark

The x-axis of the graph below is the atomic number of the elements in Period 3.

q4_3-2_hard_mcq_ib-chemistry-sl

Which variable could represent the y-axis?

  • Melting point 

  • Electronegativity

  • Ionic radius

  • Atomic radius

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161 mark

Which statement is true about all exothermic reactions?

  • Gases are formed during the reaction

  • They give out heat 

  • The reaction is fast

  • They are combustion reactions

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171 mark

A basic definition of Hess’s Law states that the overall enthalpy change for a reaction is the same independent of the route taken. 

The addition of which of the following statements makes the definition of Hess’s Law more complete? 

  1. Providing that the reactants are the same
  2. Providing that the products are the same
  3. Providing that the conditions at the start and the end of the reaction are the same
  • I and II only 

  • I and III only 

  • II and III only 

  • I, II and III

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18
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1 mark

Which compound has an Mr of 84.18 and will react with HBr to give a product with an Mr of 165.09?10-2-h-q3-ib-chemistry-mcqs

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    19
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    1 mark

    Some bond energy values are listed below.

    bond

    bond energy / kJ mol-1

    Br–Br 

    Cl–Cl

    C–H

    C–Cl

    193

    242

    414

    324

    These bond energy values relate to the following four reactions. 

    W

    Br2 → 2Br

    X

    2Cl → Cl 2

    Y

    CH3 + Cl → CH3Cl

    Z

    CH4 → CH3 + H 

    What is the correct order of enthalpy changes of the above reactions from most negative to most positive? 

    • Y → Z → W → X

    • Z → W → X → Y

    • Y → X → W → Z

    • X → Y → Z → W

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    20
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    1 mark

    A hydrocarbon, X, was burned in excess oxygen to give carbon dioxide and water as the only products. 0.1mol of X produced 9.08dm3 of carbon dioxide at standard conditions.

    What is the molecular formula of X?

    • CH4

    • C2H6

    • C3H8

    • C4H10

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    21
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    1 mark

    Which sample contains the largest amount, in mol, of atoms?

    • 0.30 mol of P2O5

    •  0.40 mol of CuSO4.5H2O

    • 0.50 mol of CH3COOH

    • 0.90 mol of H2O

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    221 mark

    The energies of the reactants, the products and the transition state of a reaction are shown in the reaction pathway diagram below.

    rGbZAS69_9

    Which expression correctly represents how to calculate the activation energy of the forward reaction?

    • E1 – E2

    • E2 – E1

    • E2 – E3

    • E3 – E2

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    231 mark

    Bleach solution contains sodium chlorate (I) which naturally decomposes according to the equation below:

    2NaClO (aq)  → 2NaCl (aq)  +  O2 (g)

    The bleach decomposes faster as the temperature increases. A 100 cm3 sample of 10% bleach was heated to 40 degreeC and the amount of oxygen evolved was measured against time.

    The experiment was repeated under the same conditions, but this time using a 100 cm3 sample of 20% bleach. If the first experiment produces the dotted line, which line is produced by the second experiment?

    hard-6

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      241 mark

      The reaction between nitrogen and hydrogen produces ammonia gas:

      N2 (g) + 3H2 (g)  rightwards harpoon over leftwards harpoon  2NH3 (g)

      If the equilibrium constant for the reaction is x, what is the equilibrium constant for the following reaction?

      2N2 (g) + 6H2 (g)  rightwards harpoon over leftwards harpoon  4NH3 (g)

      • x

      • 2x

      • x2

      • 2x2

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      251 mark

      Perbromic acid, HBrO4 , is an example of a strong acid when dissolved in water. What is true about perbromic acid?

      • HBrO4 is largely found as molecules in the solution

      • HBrO4 solution reacts only with strong bases

      • HBrO4 is fully dissociated in solution

      • HBrO4 has a pH greater than 7

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      261 mark

      In which compound are there two different elements with the same oxidation number?

      • Mg(OH)2

      • Na2SO4

      • HClO

      • NH4Cl

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      271 mark

      When sulfuric acid and sodium iodide react, one of the reactions that takes place is shown by the equation below: 

                  8NaI  +  9H2SO4  →  8NaHSO4  +  4I2  +  H2S  +  4H2

      Which species has been oxidised in this reaction?

      • I

      • SO42−

      • Na+

      • H+

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      281 mark

      Isomers X and Y both react with HBr.7KgQdxfW_10-2-m-q2-ib-chemistry-mcqs

       A mixture of X and Y is reacted with HBr.

      Which three structures represent three different possible products of this reaction?

       A  

      (CH3)2CHCBr3

         (CH3)2CBrCHBr2

       CH3CHBrCHBrCH3

      B

      (CH3)2CHCBr3

      (CH3)2CBrCHBr2

      CH3CBr2CHBrCH3

      C

      (CH3)2CBrCBr3

      (CH3)2CHCBr3

      CH3CBr2CHBrCH3

      D

      (CH3)2CBrCHBr2

      CHBr2CBr(CH3)CH3

      CH3CHBrCBr2CH3

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        291 mark

        Which statements about the chlorine free radical are correct?

        1. It has 17 electrons.
        2. It is an uncharged species.
        3. It is formed by homolytic fission.
        • I and II only

        • I and III only

        • II and III only

        • I, II and III

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        301 mark

        In the hydrolysis of bromoethane by aqueous sodium hydroxide, what is the nature of the attacking group and of the leaving group?

         

         

        attacking group

        leaving group

        A

        B

        C

        D

        electrophile

        electrophile

        nucleophile

        nucleophile

        electrophile

        nucleophile

        electrophile

        nucleophile

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