The Covalent Model (DP IB Chemistry: SL)

Exam Questions

7 hours108 questions
11 mark

Silver and iodine are both shiny crystalline solids.

Which forces exist between neighbouring iodine molecules in solid iodine and particles in solid silver?

 

iodine

silver

A

metallic bonds

covalent bonds

B

ionic bonds

metallic

C

covalent bonds

covalent bonds

D

London dispersion forces

metallic

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    21 mark

    Which of these atoms is most electronegative?

    • Cl

    • Mg

    • Br

    • Na

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    31 mark

    Based on their Pauling electronegativity values, which atom is more likely to form a covalent bond with fluorine?

     

    atom

    Pauling value

     

    fluorine

    4.0

    A

    hydrogen

    2.2

    B

    copper

    1.9

    C

    magnesium

    1.3

    D

    potassium

    0.8

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      41 mark

      Hydrazine, N2H4, is a precursor for multiple pharmaceutical compounds. 

      Which of the diagrams below illustrate the most likely structure and bond angle of hydrazine?

      ma1_14-2_ib_sl_mcq_easy

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        51 mark

        Graphite has a structure containing layers of carbon atoms in hexagonal rings.

        Why is graphite a good conductor of electricity?

        • It has delocalised ions which can move and carry charge

        • It has delocalised electrons which are mobile

        • There are only weak London forces between the layers

        • Each carbon atom in the layers has only three covalent bonds

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        61 mark

        What is the correct bond angle in a trigonal planar molecule?

        • 107°

        • 120°

        • 180°

        • 109.5°

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        71 mark

        Which statement about the physical properties of substances is correct?

        • Covalent structures always have high melting points

        • Metals only conduct electricity when solid

        • Metals always have high melting points 

        • Ionic substances conduct electricity when liquid 

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        81 mark

        Which of the following statements about graphite is correct?

        • The bond angle in graphite is 109.5 o

        • There are only London forces between the layers of graphite

        • Graphite has a higher melting point than diamond

        • Graphite is soluble in water

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        91 mark

        Which substance is described in the table below?

        Melting point

        Electrical Conductivity

        Solubility

        Very high

        Non-conductor

        Does not dissolve

        • Silicon dioxide

        • Buckminsterfullerene

        • Graphite

        • Sodium chloride 

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        101 mark

        Which of the following is the correct resonance hybrid structure of the carbonate ion, CO32-?

        q8_14-2_ib_sl_easy_mcq

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          111 mark

          Which of the following dipole labels are not correct?

          q1_4-3_ib_sl_easy_mcq

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            121 mark

            Which of the following compounds is polar?

            • CCl4

            • BF3

            • PH3

            • CH3CH3

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            131 mark

            Which of the following statements is not correct?

            • The strongest type of intermolecular force in ammonia is hydrogen bonding

            • The strongest type of intermolecular force in water is hydrogen bonding

            • The strongest type of intermolecular force in hydrogen chloride is permanent dipole 

            • The strongest type of intermolecular forces in ethanol is permanent dipole 

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            141 mark

            Which of the following statements about ethylamine, CH3CH2NH2, is correct?

            • The strongest type of intermolecular force are London dispersion forces

            • The nitrogen atom does not have a lone pair present

            • The strongest type of intermolecular force is permanent dipole permanent dipole forces

            • The strongest type of intermolecular force is hydrogen bonding

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            151 mark

            Which of the following statements about butane, CH3CH2CH2CH3, and propanone, CH3COCH3 are correct? 

            I.The boiling point of propanone is higher than butane

            II. The boiling point of butane is higher than propanone

            III. The strongest type of intermolecular force in propanone are permanent dipole permanent dipole forces

            • I and II only

            • I and III only

            • II and III only

            • I, II and III

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            16
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            1 mark

            Which element does not form stable compounds that break the octet rule?

            • Sulfur

            • Oxygen

            • Boron

            • Chlorine

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            17
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            1 mark

            What are the bond angles in a molecule with five electron domains, XY5?

             

            Axial bond angles / o

            Equatorial bond angles / o

            A.

            90

            90

            B.

            120

            90

            C.

            90

            120

            D.

            120

            120

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              18
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              1 mark

              Which compound contains delocalised electrons?

              • Cyclohexane, C6H12

              • Cyclohexene, C6H10

              • Benzene, C6H6

              • Cyclohexanol, C6H11OH

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              19
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              1 mark

              Which structure does not show resonance?

              • Carbonate ion, CO32-

              • Hydroxide ion, OH-

              • Ethanoate ion, CH3COO-

              • Nitrate ion, NO3-

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              11 mark

              Which of the following statements about 2-methylpropan-2-ol, CH3C(CH3)(OH)CH3, are correct ? 

              I.The structure contains 16 bonding pair of electrons

              II.The O-C-C bond angle is 109.5 o

              III. The total number of electrons is 32

              • I and II only 

              • I and III only 

              • II and III only 

              • I, II and III

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              21 mark

              Which of the following molecules has the biggest overall dipole?

              q2_4-1_medium_mcq_ib-chemistry-hl

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                31 mark

                 The electronegativity of four elements are given below 

                N = 3.0       H = 2.1       F = 4.0      P = 2.1      

                 What is the correct order of polarity for the following compounds

                • PH3 < PF3 < NF3 < NH3

                • PH3 < PF3 < NH3 < NF3   

                • NF3 < NH3 < PH3 < PF3 

                • PH3 < NH3 < NF3 < PF3 

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                41 mark

                Below are four molecules. Which is the most polar molecule present?

                • CH3NH2

                • CH4

                • CCl4

                • CO2

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                51 mark

                The correct order of increasing boiling points for the following compounds is

                • 1-chlorobutane < butane < butan-1-ol 

                • Butan-1-ol < 1-chlorobutane < butane, 

                • Butane < 1-chlorobutane < butan-1-ol 

                • Butan-1-ol < butane < 1-chlorobutane 

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                61 mark

                What is the strongest type of intermolecular force exhibited in the amino acid molecule serine?

                Otne2dIl_q3_4-3_ib_sl_medium_mcq
                • London dispersion forces

                • Permanent dipole permanent dipole forces

                • Hydrogen bonding

                • Covalent bonding 

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                71 mark

                Hexane, C6H14 and 2,2-dimethylbutane, CH3C(CH3)2CH2CH3, are two isomers of one another and have the same Mr of 86.0. 

                Hexane has a higher boiling point than 2,2-dimethylbutane. 

                Which of the following statements is not correct?

                • hexane has a higher boiling point because it is a straight chain molecule

                • 2,2-dimethylbutane has a lower boiling point as it is a branched molecule 

                • 2,2-dimethylbutane only contains London dispersion forces 

                • hexane contains permanent dipole permanent dipole forces

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                81 mark

                Which of the following statements about propanal and propanone are correct?

                q6_4-3_ib_sl_medium_mcq

                I.The strongest type of intermolecular force in both molecules is hydrogen bonding

                II.The strongest type of intermolecular force in both molecules is permanent dipole permanent dipole forces

                III. Both compounds are soluble in water

                • I and II only

                • I and III only

                • II and III only

                • I, II and III

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                91 mark

                Which molecule has the lowest boiling point?

                • CH3CH2CHO

                • CH3CH2CH2Cl

                • CH3CH2CH3

                • CH3CH2COOH

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                101 mark

                Boron trifluoride, BF3, reacts with trimethylamine, (CH3)3N, to form a compound of formula (CH3)3N.BF3

                How may this reaction be written using 3D structures to show  the shapes of the reactants and products?

                q2-1_14-2_ib_sl_medium_mcq

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                  111 mark

                  Which of the following statements about graphite are correct? 

                  I.   The carbon atoms are joined together by three covalent bonds

                  II.   Graphite contains delocalised electrons

                  III.   The C-C-C bond angle is 109.5o

                  • I and II only

                  • I and III only

                  • II and III only

                  • I, II and III

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                  121 mark

                  Which statement below shows the correct information about diamond and silicon?

                  • Diamond is macromolecular and silicon is simple molecular

                  • The bond angles in the two structures are the same

                  • The bond lengths are longer in C-C than in Si-Si

                  • Diamond and silicon both conduct electricity due to delocalised electrons in their structure

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                  131 mark

                  Which one of these species has a bond angle of 120°?

                  • H3O+  

                  • TlBr32-

                  • BCl3

                  • NH3 

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                  141 mark

                  Which of the following statements about silicon dioxide is correct? 

                  I.   Silicon dioxide forms a giant covalent network

                  II.  Each silicon atom is covalently bonded to four oxygen atoms

                  III.  Silicon dioxide molecules are V-shaped

                  • I and II only

                  • I and III only

                  • II and III only

                  • I, II and III

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                  151 mark

                  Ibuprofen is an anti-inflammatory drug that is used for treating pain, fever and inflammation. The structure is shown below.

                  q8_4-2_ib_sl_medium_mcq

                   

                  Ibuprofen

                   What are the correct bond angles for a and b?

                   

                  a

                  b

                  A

                  120o

                  120o

                  B

                  107o

                  109.5o

                  C

                  109.5o

                  120o

                  D

                  120o

                  109.5o

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                    161 mark

                    Which of the following molecules obeys the octet rule?

                    • BF3

                    • HCN

                    • BeCl2

                    • CS2

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                    171 mark

                    Dichlorodifluoromethane, CCl2F2, has been used in aerosol propellants and as a refrigerant.

                    Which statement helps to explain why dichlorodifluoromethane is chemically inert?

                     

                    • the carbon-fluorine bond energy is large

                    • the carbon-fluorine bond has a low polarity

                    • fluorine is highly electronegative

                    • fluorine compounds are non-flammable

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                    181 mark

                    Which species breaks the octet rule?

                    • PCl3

                    • BF4-

                    • SCl4

                    • NH4+

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                    191 mark

                    Which combination correctly describes the geometry of BrF4- ?

                     

                    Electron domain geometry around Br

                    Molecular geometry around Br

                    A

                    Octahedral

                    Tetrahedral

                    B

                    Tetrahedral

                    Square planar

                    C

                    Octahedral

                    Square planar

                    D

                    Tetrahedral

                    Tetrahedral

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                      201 mark

                      Which species contain delocalised electrons?

                      q1_14-2_ib_hl_medium_mcq
                      • I and II only

                      • I and III only

                      • II and III only 

                      • I, II and III

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                      11 mark

                      CHCl3 and Br2 are both liquids at room temperature due to the existence of dipoles.

                      What dipoles are involved within CHCl3 and Br2?

                       

                      CHCl3

                      Br2

                      A

                      induced dipoles only

                      induced dipoles only

                      B

                      induced dipoles only

                      induced dipoles and permanent dipoles

                      C

                      induced dipoles and permanent dipoles

                      induced dipoles and permanent dipoles

                      D

                      induced dipoles and permanent dipoles

                      induced dipoles only

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                        21 mark

                        Which of the following statements about 2-chloropropene, CH2C(Cl)CH3 is not correct

                        • There are 3 lone pairs in the molecule

                        • There are 24 valence electrons in the molecule 

                        • The molecule does obey the octet rule

                        • The molecule does not obey the octet rule

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                        31 mark

                        Which of the following structures do not obey the octet rule?

                        I.BeCl2

                        II.BF3

                        III. H2O

                        • I and II only

                        • I and III only

                        • II and III only

                        • I, II and III

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                        41 mark

                        Which is the shortest bond length in the following gases?

                        • oxygen-oxygen in oxygen gas, O2

                        • carbon-carbon in ethyne gas, C2H2

                        • nitrogen-nitrogen in nitrogen gas, N2

                        • oxygen-oxygen in ozone gas, O3

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                        51 mark

                        Which statement best describes the intramolecular bonding in a carbonate ion, CO32-?

                        • Only London forces

                        • Electrostatic attraction between pairs of electrons and positively charged nuclei

                        • Permanent dipole permanent dipole forces

                        • Electrostatic attraction between separate carbonate ions

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                        61 mark

                        The number of electrons in the valence shell of elements X and Y are 5 and 7 respectively. What is the formula and type of compound formed from these elements?

                        • Covalent, XY3

                        • Ionic, XY3

                        • Covalent, X3Y

                        • Ionic, X3Y

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                        71 mark

                        In which series of compounds does covalent character increase when going from left to right?

                        • KI, KBr, KCl

                        • NaI, KI, RbI

                        • NaCl, MgCl2, AlCl3

                        • SO2, P4O10, SiO2

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                        81 mark

                        Which of the following molecules will have the highest boiling point?

                        • CH3CH2CHO

                        • CH3CH2CH2NH2

                        • CH3CH2OCH3

                        • CH3CH2CH2F

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                        91 mark

                        What is the correct order of boiling points for the following molecules, from lowest to highest?

                        • CH3F < F2 < CH3CH2F < HF

                        • F2 < CH3F < CH3CH2F < HF

                        • F2 < CH3CH2F < CH3F < HF

                        • HF < CH3CH2F <C H3F < F2  

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                        101 mark

                        In which of the following processes do hydrogen bonds get broken?

                        • 2HBr (g) → H2 (g) + Br2 (g)

                        • C2H6 (l) → 2C (g) + 6H (g)

                        • H2 (l) → H2 (g)

                        • NH3 (l) → NH3 (g) 

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                        111 mark

                        Hydrogen bonding occurs between molecules of propanal, CH3CH2CHO, and molecules of liquid Y. Which of the following is most likely to be liquid Y?

                        • CH3CO2CH3

                        • CH3OH

                        • CH3COCH3

                        • CH3CHO

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                        121 mark

                        The following statements are all correct. Which of the statements can be explained, in part, by hydrogen bonding?

                        I.Ice is less dense than water

                        II.Butanone has a lower boiling point than butan-1-ol

                        III. At room temperature butanone can mix with water

                        • I and II only

                        • I and III only

                        • II and III only

                        • I, II and III

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                        131 mark

                        Hydrogen bonding can occur between propanal, CH3CH2CHO and which other molecule?

                        • CH3COOH

                        • CH3CO2CH3

                        • CH3CH2F

                        • CH3COCH3

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                        141 mark

                        Which of the following about dimethylamine, NH(CH3)2 , is correct?

                         

                        Bond angle

                        Strongest type of intermolecular force present

                        A

                        109.5

                        Permanent dipole permanent dipole forces

                        B

                        109.5

                        London dispersion forces

                        C

                        107o

                        Hydrogen bonding

                        D

                        105o

                        Hydrogen bonding

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                          151 mark

                          Which of the following statements are correct? 

                          I.The strongest type of intermolecular force between BF3 molecules are permanent dipole permanent dipole forces

                          II.The strongest type of intermolecular force between HCN molecules are permanent dipole permanent dipole forces

                          III. The bond angle in HCN is larger than the bond angle in BF3

                          • I and II only

                          • I and III only

                          • II and III only

                          • I, II and III

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                          161 mark

                          Which of the species shown below does not have resonance structures?

                          • C6H6

                          • CO32-

                          • C2H4

                          • O3

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                          171 mark

                          Below are statements about the structure and bonding in silicon dioxide. Which pair of statements is correct?

                           

                          structure

                          bonding

                          A

                          silicon dioxide molecules are bent linear

                          silicon atoms have covalent bonds to two oxygen atoms

                          B

                          silicon dioxide has a giant macromolecular structure

                          each oxygen bonds covalently to one silicon atom

                          C

                          silicon dioxide has a giant macromolecular structure

                          silicon atoms bond to four oxygen atoms

                          D

                          silicon dioxide molecules are linear

                          silicon and oxygen atoms are joined by a double covalent bond

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                            181 mark

                            Which compounds have an ionic lattice structure in the solid state?

                            I. silicon dioxide

                            II. sodium iodide

                            III.  ammonium sulfate

                            • I and II only

                            • I and III only

                            • II and III only

                            • I, II and III

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                            191 mark

                            The correct shape and bond angle for the TlBr32- ion?

                             

                            Shape

                            Bond angle

                            A

                            Pyramidal

                            120°

                            B

                            Pyramidal

                            107°

                            C

                            Tetrahedral

                            109.5°

                            D

                            Tetrahedral

                            120°

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                              201 mark

                              Which of the following is correct for the molecules of BeCl2 and BeCl42-?

                               

                              BeCl2

                              BeCl42-

                               

                              Shape

                              Bond angle

                              Shape

                              Bond angle

                              A

                              Linear

                              109.5°

                              Square planar

                              90°

                              B

                              V-shaped

                              107°

                              Square planar

                              90°

                              C

                              V-shaped

                              105°

                              Tetrahedral

                              109.5°

                              D

                              Linear

                              180°

                              Tetrahedral

                              109.5°

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                                211 mark

                                Tramadol is an example of a painkiller which is classed as an opioid analgesic. It binds to opioid receptors in the central nervous system and inhibits noradrenaline and serotonin reuptake inhibiting pain transmission 

                                The structure is shown below 

                                Which of the following are the correct bond angles for a, b and c?

                                q8_4-2_ib_sl_hard_mcq

                                 

                                a

                                b

                                c

                                A

                                120o

                                109.5o

                                107o

                                B

                                120o

                                107o

                                105o

                                C

                                107o

                                109.5o

                                107o

                                D

                                109.5o

                                107o

                                105o

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                                  221 mark

                                  Some properties of substance X are given in the following table 

                                  Melting Point

                                  Very high

                                  Strength

                                  Very strong across the layer

                                  Conductivity

                                  Excellent conductor

                                  Example of a Use

                                  Used as a coating for smartphones, tablets and computers

                                  What is a possible identity of substance X?

                                  • Graphene

                                  • Graphite

                                  • Silicon dioxide 

                                  • Buckminsterfullerene

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                                  231 mark

                                  Sulfur forms the compound S4N4 with nitrogen, the structure is shown below.

                                  q10_4-2_ib_sl_hard_mcq

                                    Which of the following statements about S4N4 is correct?

                                  • The sulfur atom marked x has two lone pairs

                                  • The sulfur atom marked y has two lone pairs

                                  • Each N atom has two lone pairs 

                                  • The N-S-N bond angle will be larger than S=N=S bond angle 

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                                  241 mark

                                  Nitrous acid is produced when nitrogen dioxide dissolves in water to produce acid rain. What is the correct Lewis structure for nitrous acid?

                                  q3-8-3-mcq-hard-ib-chemistry-sl

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                                    25
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                                    1 mark

                                    Which of the following species is polar?

                                    • ICl4-

                                    • PF5

                                    • SO3

                                    • SH2

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                                    26
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                                    1 mark

                                    Which species can be represented with only one Lewis structure?

                                    • H2PO4-

                                    • O3

                                    • CH3COCH3

                                    • 1,3 cyclohexadiene

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                                    27
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                                    1 mark

                                    In which group do both compounds contain delocalised electrons?

                                    • K2CO3 and cyclohexene, C6H10

                                    • KOH and methybenzene, C7H8

                                    • KHCO3 and buta-1,3-diene, C4H6

                                    • Methanol and sodium methanoate, HCOONa

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                                    281 mark

                                    Which row of the table is correct about the trend and explanation in the boiling points of the alcohols CH3OH, C2H5OH and C3H7OH?

                                                

                                                 Trend in boiling points                    

                                                                           Explanation                                                      

                                        A

                                    CH3OH >C2H5OH > C3H7OH 

                                    The London dispersion forces decrease with each additional CH2

                                    B

                                    CH3OH >C2H5OH > C3H7OH 

                                    The strength of the hydrogen bonds decreases with each additional CH2

                                    C

                                    C3H7OH >C2H5OH >CH3OH   

                                    The London dispersion forces increase with each additional CH2

                                    D

                                    C3H7OH >C2H5OH >CH3OH  

                                    The strength of the hydrogen bonds increases with each additional CH2

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