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Fatty Acids (DP IB Biology: SL)

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Fatty Acids: Types

  • Triglycerides are a form of lipid, made up of one molecule of glycerol with three fatty acids attached to it
  • These fatty acids have long hydrocarbon ‘tails’
  • Fatty acids occur in two forms:
    • Saturated fatty acids
    • Unsaturated fatty acids
      • Unsaturated fatty acids can be monounsaturated or polyunsaturated

  • The difference between these fatty acid types is found in their hydrocarbon tails

Saturated fatty acids

  • In saturated fatty acids, the bonds between the carbon atoms in the hydrocarbon tail are all single bonds
  • The fatty acid is said to be ‘saturated’ with hydrogen
    • This means that each carbon atom in the hydrocarbon tail (except for the final carbon atom) is bonded to two hydrogen atoms

  • Saturated fatty acids can be synthesised industrially by hydrogenation (reaction with hydrogen gas) of unsaturated fatty acids
  • All the carbon-to-carbon bonds are single bonds in saturated fatty acids

[Saturated fatty acid example.png], downloadable AS & A Level Biology revision notes

An example of a saturated fatty acid

Unsaturated fatty acids

  • In unsaturated fatty acids, the bonds between the carbon atoms in the hydrocarbon tail are not all single bonds
    • There is at least one carbon-carbon double bond; a fatty acid with one C=C double bond is known as monounsaturated fatty acid

    • In some unsaturated fatty acids, there are many carbon-carbon double bonds; these are known as polyunsaturated fatty acids
    • These double bonds can cause the hydrocarbon tail of unsaturated fatty acids to kink (bend slightly), meaning they are not as straight as saturated fatty acids

  • The fatty acid is said to be ‘unsaturated’ because the hydrocarbon tail does not contain the maximum number of hydrogen atoms possible
    • This is because each carbon atom in a carbon-carbon double bond can only bond to one hydrogen atom (instead of two)

Unsaturated fatty acid example, downloadable AS & A Level Biology revision notes

An example of a monounsaturated fatty acid

Triglycerides_Basics - types of fatty acids (2), downloadable AS & A Level Biology revision notes

An example of a polyunsaturated fatty acid

Examiner Tip

You don't need to know the names of various fatty acids, but you should be able to recognise from a diagram whether a fatty acid is saturated, monounsaturated or polyunsaturated (look for any carbon-carbon double bonds)!

Unsaturated Fatty Acids

The different isomers of unsaturated fatty acids

  • A single C-C bond in a hydrocarbon chain is able to rotate along its axis so that rotation of one part of the molecule in relation to others is possible
  • The rotation may cause conformational changes in molecules but they all remain identical
  • However, when there is a C=C double bond in a hydrocarbon chain, no rotation is possible
  • This causes isomers of fatty acids to be formed, each with different properties
  • The isomers are labelled cis and trans isomers

Cis-isomers

  • At a C=C double bond, the attached hydrogen atoms are on the same side of the hydrocarbon chain as each other
    • This causes a kink in the fatty acid chain which means the fatty acid chains are less tightly packed together, lowering their melting point (less kinetic energy is needed to break them apart)
    • Triglycerides that contain cis-unsaturated fatty acids are liquid (oils) at room temperature

Cis- Fatty Acid Structure, downloadable IB Biology revision notes

The Structural Differences Between a Saturated and a Cis-Unsaturated Fatty Acid

Trans-isomers

  • At a C=C double bond, the attached hydrogen atoms are on the opposite sides of the hydrocarbon chain to each other
    • The lack of bend in the hydrocarbon chain allows them to pack more closely together meaning they have a higher melting point (this property makes them more attractive to food manufacturers)
    • Triglycerides that contain trans-saturated fatty acids are solid are room temperature

Trans- Fatty Acid Structure, downloadable IB Biology revision notes

The Structure of a Trans-Unsaturated Fatty Acid

Fatty Acids: Health Risks

The use of trans-fatty acids in the food industry

  • Trans-fatty acids occur in small quantities in natural products such as dairy and red meat
  • Artificial trans-fats (which contain trans-fatty acids) are made industrially by the hydrogenation of liquid vegetable oils
  • Trans-fats are favoured by food manufacturers for commercial reasons
    • They are more solid at room temperature
    • They create more stable emulsions in shortening agents
    • Food products with trans-fats appear (in their retail packaging) drier and less 'greasy' to consumers
    • Alleged taste benefits (though this is subjective)
    • They can be reused more times eg. in large-scale deep-fat fryers
    • Many countries have legislated to restrict the use of trans-fats in the foodservice industry

  • Many foods that contains trans-fats (often labelled as 'partially hydrogenated vegetable oils') are sold as processed products in supermarkets
    • Biscuits/cookies
    • Cakes
    • Doughnuts
    • Pie crusts
    • Crisps
    • Pizza bases
    • Certain kinds of margarine and spreads

Trans-fatty acids have associated health risks

  • The two types of fat that lead to health problems are namely saturated fats and trans-fats
    • Doctors recommend limiting your intake of these types of fats

  • Trans-fats alter the balance of various types of cholesterol
    • They increase low-density lipoprotein (LDL) levels in circulation (so-called 'bad' cholesterol)
    • They decrease high-density lipoprotein (HDL) levels in circulation (so-called 'good' cholesterol)

  • LDLs are known to increase the risk of coronary heart disease, blood clotting and strokes
  • Doctors recommend that the bulk of fats intake should come from monounsaturated fats, which reduce LDL levels
    • Omega-3 fats and oils are a well-publicised source of monounsaturated fats; these are found in fish, pulses and certain nuts

Buildup of plaque in the coronary arteries, IGCSE & GCSE Biology revision notesExcess consumption of trans-fatty acids and saturated fats can lead to the buildup of cholesterol and the blockage of coronary arteries, causing Coronary Heart Disease (CHD)

Evaluating claims

  • Evidence for the claims surrounding the health risks associated with trans-fats often comes from 'cohort studies'
    • Eg. Greenland Eskimos, whose diet is rich in oily fish and meat, have a very low incidence of heart disease

  • Other epidemiological studies can establish correlations between diet and incidence of disease
  • Whilst it is rare to find a direct causal link between fat intake and heart disease, the many claims about fats suggest strongly that trans-fats have an overall detrimental effect on health when consumed in high quantities
  • Other conditions linked to trans-fats include
    • Allergy
    • Breast cancer
    • Colonic cancer
    • Cardiovascular diseases
    • Premature birth
    • Preeclampsia (a condition associated with pregnancy)
    • Disorders of the nervous system
    • Vision defects in infants
    • Diabetes
    • Obesity

Examiner Tip

  • It is important to remember that correlation does not always mean causation
    • Correlation is an association or relationship between variables
    • Causation occurs when one variable has an influence or is influenced by, another
    • There is a clear distinction between correlation and causation: a correlation does not necessarily imply a causative relationship

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Phil

Author: Phil

Expertise: Biology

Phil has a BSc in Biochemistry from the University of Birmingham, followed by an MBA from Manchester Business School. He has 15 years of teaching and tutoring experience, teaching Biology in schools before becoming director of a growing tuition agency. He has also examined Biology for one of the leading UK exam boards. Phil has a particular passion for empowering students to overcome their fear of numbers in a scientific context.