Syllabus Edition

First teaching 2023

First exams 2025

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Particles in the Atom & Atomic Radius (CIE AS Chemistry)

Exam Questions

1 hour21 questions
1a4 marks

Complete Table 1.1 to show the relative charge and mass of the subatomic particles.

Table 1.1

Subatomic particle Relative Charge Relative Mass
Proton   1
Neutron    

Electron

  1 over 1836

1b
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3 marks

Using the Periodic Table, complete Table 1.2 to show the number of protons, neutrons and electrons in each of the given species.

Table 1.2

Species Number of protons Number of neutrons Number of electrons 
31P      
24Na+      
37Cl      

1c2 marks

State why the physical properties of isotopes are different.

1d2 marks

Explain why the chemical properties of 35Cl and 37Cl are similar.

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2a1 mark

Fig. 5.1 shows how protons, neutrons and electrons behave differently when they move at the same velocity in an electric field.

Label the positive and negative plates in Fig. 5.1.

129c5fc8-2d7a-4e7d-be1d-139c459aad6d
 
Fig. 5.1
2b3 marks

Using the Periodic Table, complete Table 5.1 to show the number of protons, neutrons and electrons in each of the given species.

Table 5.1
 
Symbol Protons Neutrons Electrons
23Na      
32S2–      
86Sr2+      
 
2c1 mark

Write the electronic configuration for the 32S2– atom.

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1a3 marks

The Bohr model of an atom represents a central nucleus, consisting of protons and neutrons, with electrons surrounding it moving in circular orbits. This model was proposed by Niels Bohr in 1913 and after some further research, energy levels and sublevels were recognised, and the model was refined.  

Using your knowledge of atomic structure, complete Table 1.1 below for the particles found in an atom. 

Table 1.1

Particle

Relative charge

Relative mass

Proton

   

Neutron

   

Electron

   
1b2 marks

State the block in the Periodic Table in which silicon is placed. Explain your answer.

1c3 marks

A mass spectrometer can be used to detect isotopes of an element, such as silicon. For these to be detected in the mass spectrometer, a sample containing the isotopes must first be vapourised and then ionised.

Give two reasons why the sample of isotopes must be ionised, and state what could be adjusted in order to allow ions formed by different isotopes to reach the detector.

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2a2 marks

Using your Periodic Table, complete Table 1.1

Table 1.1

Symbol Protons Neutrons Electrons
23Na      
32S2-      
86Sr2+      
2b3 marks

Sodium is an element in Period 3. State and explain the trend in atomic radius across the period.

Trend ...........................................................................................................................................

Explanation .................................................................................................................................

2c3 marks

Chlorine is an element in Period 3 which has an atomic radius of 99 pm. The chloride ion has an ionic radius of 167 pm.

Explain the difference between the two radii.

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3a2 marks

The composition of atoms and ions can be determined from knowledge of atomic number, nucleon number and charge.

Complete Table 3.1.

Table 3.1 

Atomic number Nucleon number Number of electrons Number of protons Number of neutrons Symbol 
15         begin mathsize 14px style P presubscript 15 presuperscript 31 superscript 3 minus sign end superscript end style
    18 17 19  
3b3 marks

Beams of protons, neutrons and electrons behave differently in an electric field due to their differing properties.

Fig. 3.1 shows the path of a beam of electrons in an electric field.

Add and label lines to Fig. 3.1 to represent the paths of beams of electrons and neutrons in the same field.

proton-beam

Fig. 3.1

3c2 marks

Chlroine and sulfur are in Period 3. Outline why the chlorine atom has a smaller atomic radius than the sulfur atom.

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1a6 marks

Table 4.1 below shows the atomic radii for the elements of Period 2, Li to F.

Table 4.1 

Element

Li Be B C N O F
Atomic radius / pm 152 112 88 77 70 66 64

 

i)
Explain the variation in atomic radius.
 
[4]
 
ii)
The value for neon is missing in Table 4.1. Explain why the atomic radius of neon cannot be measured in the same way as the other Period 2 elements.
 
[2]
1b1 mark

Complete Fig. 4.1 to show the electronic configuration of boron in the excited state.

 
1-1-atomic-structure-2c-a
 
Fig. 4.1
1c2 marks

Explain why the first ionisation energy of boron is lower than the first ionisation of beryllium.

1d1 mark

The successive ionisation energies for another element, J, are shown in Table 4.2.

 
Table 4.2
 

Energy number

1st

2nd

3rd

4th

5th

Ionisation energy value / kJ mol−1 

738

1450

7733

10543

13630

 

State the formula of the compound when element reacts with chlorine. 

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