Determining Subatomic Structure (CIE AS Chemistry)

• An atom is neutral and has no overall charge
• Ions on the other hand are formed when atoms either gain or lose electrons, causing them to become charged
• The number of subatomic particles in atoms and ions can be determined given their atomic (proton) number, mass (nucleon) number and charge

Protons

• The atomic number of an atom and ion determines which element it is
• Therefore, all atoms and ions of the same element have the same number of protons (atomic number) in the nucleus
  • E.g. lithium has an atomic number of 3 (three protons) whereas beryllium has atomic number of 4 (4 protons)

• The number of protons equals the atomic (proton) number
• The number of protons of an unknown element can be calculated by using its mass number and number of neutrons:

Mass number = number of protons + number of neutrons

Number of protons = mass number - number of neutrons

Worked example: Determine the number of protons

Answer

• Answer 1: The atomic number of a magnesium atom is 12 suggesting that the number of protons in the magnesium element is 12
  • Therefore the number of protons in a Mg²⁺ ion is also 12

• Answer 2: The atomic number of a carbon atom is 6 suggesting that a carbon atom has 6 protons in its nucleus
• Answer 3: Use the formula to calculate the number of protons

Number of protons = mass number - number of neutrons

Number of protons = 63 - 34

Number of protons = 29

• • Element X is therefore copper

Electrons

• An atom is neutral and therefore has the same number of protons and electrons
• Ions have a different number of electrons to their atomic number depending on their charge
  • A positively charged ion has lost electrons and therefore has fewer electrons than protons
  • A negatively charged ion has gained electrons and therefore has more electrons than protons

Worked example: Determine the number of electrons

Answer

• Answer 1: The atomic number of a magnesium atom is 12 suggesting that the number of protons in the neutral magnesium atom is 12
  • However, the 2+ charge in Mg²⁺ ion suggests it has lost two electrons
  • It only has 10 electrons left now

• Answer 2: The atomic number of a carbon atom is 6 suggesting that the neutral carbon atom has 6 electrons orbiting around the nucleus
• Answer 3: The number of protons of element X can be calculated by:

Number of protons = mass number - number of neutrons

Number of protons = 63 - 34

Number of protons = 29

• • The neutral atom of element X  therefore also has 29 electrons

Neutrons

• The mass and atomic numbers can be used to find the number of neutrons in ions and atoms:

Number of neutrons = mass number (A) - number of protons (Z)

Worked example: Determine the number of neutrons

Answer

• Answer 1: The atomic number of a magnesium atom is 12 and its mass number is 24

Number of neutrons = mass number (A) - number of protons (Z)

Number of neutrons = 24 - 12

Number of neutrons = 12

• • The Mg²⁺ ion has 12 neutrons in its nucleus

• Answer 2: The atomic number of a carbon atom is 6 and its mass number is 12

Number of neutrons = mass number (A) - number of protons (Z)

Number of neutrons = 12 - 6

Number of neutrons = 6

• • The carbon atom has 6 neutrons in its nucleus

• Answer 3: The atomic number of an element X atom is 29 and its mass number is 63

Number of neutrons = mass number (A) - number of protons (Z)

Number of neutrons = 63 - 29

Number of neutrons = 34

• • The neutral atom of element X has 34 neutrons in its nucleus