Ozone Depletion (AQA AS Chemistry)

Fluorohalogenoalkanes

• The most common halogenoalkanes are chlorofluorocarbons (CFCs)
• These compounds contain carbon atoms with chlorine and fluorine atoms attached to them
  • E.g. CCl₃F and CCl₂F₂

• CFCs have many uses due to their chemical inertness as they are non-flammable and non-toxic
  • They are used as refrigerators
  • Propellants for aerosols
  • As solvents for dry cleaning

Hydrofluorocarbons

• Hydrofluorocarbons (HFCs) are compounds that contain a carbon attached to hydrogen and fluorine atoms only
  • Eg. CH₂F-CF₃

• As with CFCs, HFCs are chemically inert and are therefore used for a wide range of purposes

• Though chlorofluorocarbons (CFCs) have many beneficial uses, they also have devastating effects on the ozone layer:
  • CFCs absorb a lot of UV radiation in the upper atmosphere
  • The CFCs are then broken down by the UV light causing the formation of chlorine radicals
  • These radicals react with ozone and break down the ozone layer

• This is why hydrofluorocarbons (HFCs) are often used as an alternative to CFCs
• As these compounds don’t contain any chlorine atoms, they will not have adverse effects on the ozone layer

Chlorine radicals and the ozone layer