Acid-Base Titrations (College Board AP® Chemistry)

Exam Questions

40 mins15 questions
11 mark

Indicator

pKa

Methyl orange

3.7

Phenolphthalein

9.6

Phenol red

7.9

Bromothymol blue

7.0

The pH range of four different indicators are given in the table. Which indicator would be suitable for a titration involving hydrochloric acid and ammonia?

  • Methyl orange

  • Phenolphthalein

  • Phenol red

  • Bromothymol blue

Did this page help you?

21 mark
PH curve

Which type of titration is indicated by the pH curve above?

  • Strong acid - strong base

  • Weak acid - weak base

  • Strong acid - weak base

  • Weak acid - strong base

Did this page help you?

31 mark

A 0.10 mol dm-3 solution of propanoic acid is titrated with 0.10 mol dm-3 potassium hydroxide.

Which of the following statements accurately describes this titration

  • The equivalence point occurs at pH 7.

  • The salt formed hydrolyzes to form an acidic salt.

  • The salt formed at the equivalence point is CH3COOK.

  • At the half-equivalence point, [CH3CH2COOH] = [CH3CH2COO-].

Did this page help you?

41 mark

During a titration, 23.70 cm3 of 0.02 mol dm-3 potassium hydroxide (KOH) is used to completely neutralize 0.03 mol dm-3 sulfuric acid (H2SO4).

What is the required volume of H2SO4 solution to reach the equivalence point?

  • 7.90 cm3

  • 31.65 cm3

  • 15.80 cm3

  • 17.78 cm3

Did this page help you?

51 mark

The table below shows the pKa values of four acid-base indicators:

Indicator

pKa

Methyl orange

3.7

Phenolphthalein

9.6

Phenol red

7.9

Bromothymol blue

7.0

Which indicator would be most appropriate for a titration between hydrochloric acid and ammonia?

  • Methyl orange

  • Phenolphthalein

  • Phenol red

  • Bromothymol blue

Did this page help you?

11 mark

In a titration, the equivalence point is reached when 23.70 mL of 0.02 M potassium hydroxide reacts with 0.03 M of sulfuric acid. What volume of acid is needed?

  • 7.9 mL

  • 31.65 mL

  • 15.80 mL

  • 17.78 mL

Did this page help you?

21 mark

The acid–base indicator bromophenol blue changes colour from yellow to blue over a pH range of 3.0–4.6. Which statement(s) is/are correct?

I. The pKa is between 3.0 and 4.6

II. In a neutral solution [HIn] > [In-]

III. It is a suitable indicator for a strong acid, weak base titration

  • I and II only

  • I and III only

  • II and III only

  • I, II and III

Did this page help you?

31 mark
5-6-chem--q3


The pH curve above represents a weak acid, strong base titration. The pH of the acid at half equivalence point is 4.90.

What is the Ka of the acid?

  • 4.90

  • 8.72

  • 1.26 x 10-5

  • 1.91 x 10-9

Did this page help you?

41 mark

A titration is carried out using 25.00 cm3 of 0.100 mol dm-3 propanoic acid and 0.100 mol dm-3 sodium hydroxide. Phenolphthalein (pH range: 8.3 – 10.0) is used to determine the equivalence point.

If 0.100 mol dm-3 hydrochloric acid is used instead of propanoic acid, which of the following remains unchanged?

  • The volume of base required to reach the equivalence point.

  • The pH at the equivalence point.

  • The y-intercept of the pH curve.

  • The color of the solution just before equivalence is reached.

Did this page help you?

51 mark

The pKb value of HPO42- is 6.8.

What is its conjugate acid and what is the Ka value?

  • H2PO4-, 7.2

  • H3PO4, 7.2

  • H3PO4, 1.67 x 10-7

  • H2PO4-, 6.3 x 10-8

Did this page help you?

61 mark

Which of the following salts would produce a solution with the highest pH if dissolved in water?

  • RbCl

  • CuSO4

  • KCl

  • Na2CO3

Did this page help you?

71 mark

The table below shows data for the and values for some acids and bases at 298 K.

Acid

Ka

Base

pKb

C5H6OH

1.02 x 10-10

(C2H5)3N

3.25

O2NC6H4OH

7.08 x 10-8

C6H5NH2

9.13

Which two formulas represent the weakest acid and the weakest base in the table?

  • C5H6OH and C6H5NH2

  • O2NC6H4OH and C6H5NH2

  • O2NC6H4OH and (C2H5)3N

  • C5H6OH and (C2H5)3N

Did this page help you?