Chemical Bonding (College Board AP® Chemistry)

Exam Questions

13 mins13 questions
11 mark

In which of the following pairs is the first element expected to have a higher electronegativity than the second?

  • Li, Be

  • Mg, Sr

  • Be, Al

  • Br, Cl

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21 mark

Which of the following is a non-polar molecule containing polar bonds?

  • CH3-CH3

  • CH3-CF3

  • CH2=CH2

  • CF2=CF2

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31 mark

Which of the following molecules are paired correctly with their property?

  • C2H6, good electrical conductivity

  • CaCl2, low boiling point

  • NH3, poor electrical conductivity

  • CuCl2, insoluble in water

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41 mark

Which statement is true about metallic solids?

  • Atoms are loosely packed into metallic lattices

  • Atoms lose valence electrons to become negative ions in a sea of delocalized electrons

  • Metals are held together by Coulombic forces of attraction between positive ions and delocalized electrons

  • The inner electrons of metal atoms dissociate leading to the formation of metal ions

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51 mark

Which of the following should be considered when determining the Coulombic force between ions?

I. The charge of the ions

II. The mass of the ions

III. The distance between the ions

  • I only

  • II only

  • I and II only

  • I and III only

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61 mark

Which of the following bonds is likely to have the least ionic character?

  • B-F

  • C-N

  • Mg-O

  • Si-Cl

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11 mark

The diagram below shows the potential energy as two chlorine atoms approach each other.

Graph showing potential energy versus internuclear distance for chlorine atoms forming a chlorine molecule.

As the two chlorine atoms appraoch each other, there is a decrease in energy. This decrease is because

  • two nuclei are more strongly attracted to two electrons because their magnetic fields interact more strongly.

  • the effective nuclear charge increases as the atoms approach each other.

  • the additional attractive force between the two electrons and their opposite nuclei is greater than their repulsive forces.

  • the core shielding by the electrons diminishes as the two nuclei get closer.

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21 mark

Which statement best describes the intramolecular bonding in a carbonate ion, CO32-?

  • Only London forces

  • Electrostatic attraction between pairs of electrons and positively charged nuclei

  • Permanent dipole permanent dipole forces

  • Electrostatic attraction between separate carbonate ions

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31 mark

Which of the following compounds has the strongest force of attraction between the anion and cation?

  • RbI

  • CsI

  • CaO

  • SrS

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41 mark

Which of the following statements accounts for the difference in the polarity of the BF3 and NF3 molecules?

  • Bond order

  • Bond polarity

  • Bonding type

  • Molecular geometry

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51 mark

Element

Electronegativity

H

2.1

F

4.0

Si

1.8

S

2.5

Sn

2.0

Te

2.1

Based on the information in the table, which of the following arranges the bonds in order of increasing polarity?

  • Si-H > S-F > Sn-Te

  • Sn-Te > S-F > Si-H

  • Si-H > Sn-Te > S-F

  • Sn-Te > Si-H > S-F

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11 mark

The graph below shows the potential energy as a function of internuclear distance for sulfur dioxide, SO2, and an unknown heteronuclear diatomic molecule, A-B.

Graph showing potential energy versus internuclear distance for SO₂ and AB, with curves indicating energy changes and bond behaviour.

Based on the data in the graph, which of the following correctly identifies the diatomic molecule A-B?

  • Br-F

  • Cl-Cl

  • N≡N

  • S=S

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21 mark

The graph below shows the potential energy as a function of internuclear distance for two unknown diatomic molecules, A and B.

Graph of potential energy versus internuclear distance showing two curves, marked A and B, with different minima, representing molecular interactions.

Which pair of diatomic molecules best represents A and B?

Molecule A

Molecule B

A

N≡N

I-I

B

O=O

Br-Br

C

H-Cl

Cl-Cl

D

C≡O

H-H

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