Ionization Energy (College Board AP® Chemistry)

When analyzing the ionization energy between atoms, the shielding effect (effective nuclear charge) and the distance from the nucleus have more impact than the nuclear charge

Estimate which first ionization energy is greater, F or Cl.

Answer:

• Step 1: Analyze nuclear charge

  • The nuclear charge is determined by the number of protons in the nucleus

    • Chlorine (Cl): Z = 17 (17 protons)

    • Fluorine (F): Z = 9 (9 protons)

  • Chlorine has more protons (Z) than fluorine, so its nuclear charge (Z) is greater and the Coulombic attraction should be greater

• Step 2:  Analyze distance from the nucleus

  • Chlorine has its outermost electron in the 3p subshell

  • Fluorine has its outermost electron in the 2p subshell

  • The distance from the nucleus is greater in Cl, therefore the electron in Cl experiences less Coulombic attraction from the nucleus

• Step 3: Analyzing the shielding effect (effective nuclear charge):

  • The valence electrons in Cl experience more shielding from the core electrons compared to fluorine, because there is an extra shell filled with electrons in Cl. Therefore, the effective nuclear charge is weaker in Cl

• Step 4: Estimate ionization energy

  • Based on the factors we've analyzed, we can make an estimation

  • Even if the nuclear charge is greater in Cl,

    • The distance from the nucleus is smaller in F

    • The effective nuclear charge is greater in F

  • Therefore, the coulombic force of attraction experienced by the valence electrons is stronger in F. This means that it requires more energy to remove a valence electron from a F atom compared to a Cl atom

It is compulsory to make reference to the Coulomb’s Law in every estimation of ionization energies between atoms